IP Library Granted Patent US 9,175,218
Granted Patent B2
US 9,175,218 · App. 14/368,995 · Granted Nov 3, 2015

Liquid crystal composition and liquid crystal display element

Inventors: Joji Kawamura (Saitama, JP); Masahiro Niwa (Kita-adachi-gun, JP); Makoto Negishi (Kita-adachi-gun, JP); Yoshinori Iwashita (Kita-adachi-gun, JP)
Assignee: DIC CORPORATION
C09K19/0403C09K19/12C09K2019/0407C09K2019/0466C09K2019/123C09K2019/3016G02F1/1333G02F1/13394
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Quick Facts
Patent No.
US 9,175,218
App. No.
14/368,995
Granted
Nov 3, 2015
Kind
B2
Abstract

There is provided a liquid crystal composition comprising: at least one kind of a compound represented by the following formula (i); and at least one kind of a compound represented by the following formula (ii). In the formulae, each of R i1 , R i2 and R ii1 independently represents an alkyl group having a carbon number of 1-8; one of the alkyl groups, or two or more of the alkyl groups being noncontiguous, include —CH 2 — which can be independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO— or —OCO—; hydrogen atom in the alkyl group can be substituted by fluorine atom or chlorine atom; and each of X i1 , X i2 , X i3 and X i4 independently represents hydrogen atom or fluorine atom.

Claims (38)

1. A liquid crystal composition having a positive value of Δ∈, comprising:

at least one kind of a compound represented by the following formula (i); and

at least one kind of a compound represented by the following formula (ii):

wherein in the formulae, each of R i1 , R i2 and R ii1 independently represents an alkyl group having a carbon number of 1-8;

one of the alkyl groups, or two or more of the alkyl groups being noncontiguous, include —CH 2 — which can be independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO— or —OCO—;

hydrogen atom in the alkyl group can be substituted by fluorine atom or chlorine atom; and

one of X i1 , X i2 , X i3 and X i4 represents fluorine atom, and the others of X i1 , X i2 , X i3 and X i4 represent hydrogen atom.

2. The liquid crystal composition according to claim 1 , wherein X i1 , X i3 and X i4 in the formula (i) are hydrogen atom, and X i2 represents fluorine atom.

3. The liquid crystal composition according to claim 1 , further comprising a compound represented by formula (L);

Formula 2

R L1 —B L1 -L L1 -B L2 L L2 -B L3 OL R L2   (L)

wherein in the formula, each of R L1 and R L2 independently represents an alkyl group having a carbon atom number of 1-8;

one of the alkyl groups, or two or more of the alkyl groups being noncontiguous, include —CH 2 — which can be independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO— or —OCO—;

OL represents 0, 1, 2 or 3;

each of B L1 , B L2 and B L3 independently represents a group selected from the group consisting of (a) and (b) below;

(a): 1,4-cyclohexylene group (in which one of —CH 2 — groups or noncontiguous two of —CH 2 — groups can be substituted with —O—); and

(b): 1,4-phenylene group (in which one of —CH═ group or noncontiguous two of —CH═ group can be substituted with —N═);

at least one hydrogen atom in the group (a) and the group (b) can be independently substituted with cyano group, fluorine atom or chlorine atom;

each of L L1 and L L2 independently represents single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —COO—, —OCO—, —OCF 2 —, —CF 2 O—, —CH═N—N═CH—, —CH═CH—, —CF═CF— or —C≡C—;

when OL is 2 or 3 so that plural groups of L L2 exist, said plural groups of L L2 can be the same or different;

when OL is 2 or 3 so that plural groups of B L3 exist, said plural groups of B L3 can be the same or different; and

however, the compound represented by formula (L) is not the compound represented by the formula (i) or the compound represented by the formula (ii).

4. The liquid crystal composition according to claim 1 , further comprising a compound represented by formula (M);

wherein in the formula, R M1 represents an alkyl group having a carbon atom number of 1-8;

one of the alkyl groups, or two or more of the alkyl groups being noncontiguous, include —CH 2 — which can be independently substituted by —CH═CH—, —C≡C—, —O—, —CO—, —COO— or —OCO—;

PM represents 0, 1, 2 3 or 4;

each of C M1 and C M2 independently represents a group selected from the group consisting of (d) and (e) below;

(d): 1,4-cyclohexylene group (in which one of —CH 2 — groups or noncontiguous two of —CH 2 — groups can be substituted with —O— or —S—); and

(e): 1,4-phenylene group (in which one of —CH═ groups or noncontiguous two of —CH═ groups can be substituted with —N═);

at least one hydrogen atom in the group (d) and the group (e) can be independently substituted with cyano group, fluorine atom or chlorine atom;

each of K M1 and K M2 independently represents single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —OCF 2 —, —CF 2 O—, —COO—, —OCO— or —C≡C—,

when PM is 2, 3 or 4 so that plural groups of K M1 exist, said plural groups of K M1 can be the same or different;

when PM is 2, 3 or 4 so that plural groups of C M2 exist, said plural groups of C M2 can be the same or different;

each of X M1 and X M3 independently represents hydrogen atom, chlorine atom or fluorine atom; and

X M2 represents hydrogen atom, fluorine atom, chlorine atom, cyano group, trifluoromethyl group, fluoromethoxy group, difluoromethoxy group, trifluoromethoxy group or 2,2,2-trifluoroethyl group.

5. A liquid crystal display element using the composition of claim 1 .

6. A liquid crystal display element using the composition of claim 1 , useful for IPS mode, OCB mode, ECB mode, VA mode, VA-IPS mode or FFS mode.

7. A liquid crystal display using the liquid crystal display element of claim 5 .

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2024
From: DIC CORPORATION
To: SHIJIAZHUANG CHENGZHI YONGHUA DISPLAY MATERIAL CO., LTD.
Reel/Frame 067528/0688 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 26, 2014
From: KAWAMURA, JOJI; NIWA, MASAHIRO; NEGISHI, MAKOTO; IWASHITA, YOSHINORI
To: DIC CORPORATION
Reel/Frame 033189/0469 →
Continuity (1)
Related Publication 20150108403A1 · Apr 23, 2015