Continuous fixed-bed catalytic reactor and catalytic reaction method using same
View Patent ↗A continuous fixed-bed catalytic reactor includes an inflow path for raw material gas for a catalytic reaction and an outflow path for reformed gas, a catalytic reaction container that is connected to the inflow path and the outflow path and holds a clumpy catalyst, catalyst holders that have a ventilation property and hold the clumpy catalyst, and a driving mechanism that moves the clumpy catalyst up and down by moving the catalyst holders up and down.
1. A continuous fixed-bed catalytic reactor comprising:
an inflow path for raw material gas for a catalytic reaction and an outflow path for reformed gas;
a catalytic reaction container that is connected to the inflow path and the outflow path and holds a clumpy catalyst, the clumpy catalyst having external dimensions of 5 mm to 50 mm;
a catalyst holder that has a ventilation property and holds the clumpy catalyst; and
a driving mechanism that moves the clumpy catalyst up and down by moving the catalyst holder up and down,
wherein a space for storing a solid or liquid foreign substance generated in a catalyst layer is provided below the catalyst layer; wherein the catalyst layer is a collection of clumpy catalyst particles.
2. The continuous fixed-bed catalytic reactor according to claim 1 ,
wherein at least some of catalyst particles configuring side outer circumferential surfaces of the catalyst layer are in contact with an inner wall of the catalytic reaction container.
3. The continuous fixed-bed catalytic reactor according to claim 2 ,
wherein a height of the catalyst layer is twice or less a thickness of the catalytic reaction container and is equal to or more than a maximum height of three catalyst particles overlaid in a vertical direction value.
4. The continuous fixed-bed catalytic reactor according to claim 2 ,
wherein an average speed of the driving mechanism moving the catalyst holder down is faster than an average speed of the driving mechanism moving the catalyst holder up.
5. The continuous fixed-bed catalytic reactor according to claim 2 ,
wherein the catalyst holder has a plurality of pins which are disposed in parallel with each other and which directly hold the clumpy catalyst at a front end section.
6. The continuous fixed-bed catalytic reactor according to claim 5 ,
wherein an inter-shaft distance between adjacent pins in the plurality of the pins satisfies a condition of [inter-shaft distance between pins]−[outer diameter dimension of pin]<[minimum mesh size dimension allowing the clumpy catalyst to pass through].
7. The continuous fixed-bed catalytic reactor according to claim 5 ,
wherein a curvature at a contact section in the pin with the clumpy catalyst is smaller than a maximum curvature on an outer surface of the clumpy catalyst.
8. The continuous fixed-bed catalytic reactor according to claim 1 ,
wherein the catalyst holder includes
central rods forming catalyst particle series by penetrating a plurality of the clumpy catalyst particles without impairing mobility of the clumpy catalyst, and
a holding plate supporting the plurality of the central rods upright.
9. The continuous fixed-bed catalytic reactor according to claim 8 ,
wherein a material with a high thermal conductivity is used for the central rods, and a heating apparatus is provided to heat end sections of the central rods.
10. The continuous fixed-bed catalytic reactor according to claim 8 ,
wherein the driving mechanism is operated so that a speed of the central rod becomes slower than a speed of the clumpy catalyst particles at a terminal portion of reciprocal movement by the driving mechanism.
11. The continuous fixed-bed catalytic reactor according to claim 1 ,
wherein the raw material gas is gas containing hydrocarbon, and products of a catalytic reaction are gas and solid hydrocarbon or solid carbon.
12. The continuous fixed-bed catalytic reactor according to claim 11 ,
wherein the raw material gas is gas containing tar.
13. The continuous fixed-bed catalytic reactor according to claim 12 ,
wherein the clumpy catalyst is a complex oxide containing nickel, magnesium, cerium and aluminum, and is made of a complex oxide not containing alumina,
in which the complex oxide may be made of crystal phases of NiMgO, MgAl 2 O 4 and CeO 2 .
14. The continuous fixed-bed catalytic reactor according to claim 12 ,
wherein the clumpy catalyst is made of a complex oxide containing nickel, magnesium, cerium, zirconium and aluminum,
in which the complex oxide includes crystal phases of NiMgO, MgAl 2 O 4 and Ce x Zr 1-x O 2 (0<x<1).
15. The continuous fixed-bed catalytic reactor according to claim 12 ,
wherein the clumpy catalyst is a catalyst for reforming tar-containing gas that is a complex oxide represented by aM.bNi.cMg.dO,
in which a, b and c satisfy a+b+c=1, 0.02≦a≦0.98, 0.01≦b≦0.97 and 0.01≦c≦0.97, d represents a value at which oxygen and a positive element becomes electrically neutral,
M represents at least one element selected from Ti, Zr, Ca, W, Mn, Zn, Sr, Ba, Ta, Co, Mo, Re, platinum, rhenium, palladium, rhodium, Li, Na, K, Fe, Cu, Cr, La, Pr and Nd,
at least one oxide selected from silica, alumina and zeolite is added to the complex oxide, and an amount of the oxide selected from silica, alumina and zeolite is in a range of 1% by mass to 90% by mass with respect to the complex oxide.
16. A continuous fixed-bed catalytic reaction method,
wherein a catalytic reaction is caused using the continuous fixed-bed catalytic reactor according to claim 1 .