Production method for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery
A production method for non-aqueous electrolyte secondary batteries includes a conditioning process in which an electrode group having a positive electrode and a negative electrode wound by interposing a separator therebetween is inserted inside a case a non-aqueous electrolyte including an overcharge additive is injected and the case is sealed, after which a restraining pressure is applied to the case, and charge/discharge is performed at least once. After initial charging in the conditioning process, a fracture portion is formed in secondary particles of a positive electrode active material, and then a conductive coating is formed on the fracture portion.
1. A method for producing a non-aqueous electrolyte secondary battery, the method including: inserting an electrode group having a positive electrode and a negative electrode wound by interposing a separator therebetween into a case; injecting a non-aqueous electrolyte solution containing an overcharge additive and hermetically closing the case; and then performing a conditioning process to charge and discharge the battery at least once or more while applying restraining pressure to the case,
wherein the conditioning process includes:
subjecting the battery to an initial charge at lower restraining pressure than normal restraining pressure;
forming a fracture portion in secondary particles of a positive active material after the initial charge by performing overdischarge at a high rate and at a restraining pressure which is lower than the normal restraining pressure;
forming a conductive coating on an intrinsic surface of the fracture portion by, performing recharge at the restraining pressure lower than the normal restraining pressure and at a low rate, and raising an upper limit potential during the recharge to a decomposition potential of the overcharge additive, and
wherein the normal restraining pressure is in a range of 450 to 500 kPa, the high rate is 2C or higher, and the low rate is 1C.
2. The method for producing a non-aqueous electrolyte secondary battery according to claim 1 , wherein, after the conductive coating is formed, the restraining pressure is set to the normal restraining pressure and redischarge is performed at the low rate.
3. The method for producing a non-aqueous electrolyte secondary battery according to claim 1 , wherein the secondary particles of the positive active material has an average particle diameter of 4 μm or more.