Aramid copolymer yarn having low residual sulfur
The present invention concerns yarn comprising polymer, the polymer comprising imidazole groups, the yarn having a sulfur content of 0.01 to 3.0 percent by weight, based on weight of the yarn, the yarn having a tenacity of 30 cN/dtex (33.3 gpd) or higher.
1. A yarn comprising aramid copolymer, said copolymer comprising protonated imidazole groups containing associated sulfate anions, the yarn having a sulfur content of 0.1 to 3 percent by weight, based on weight of the yarn, the yarn having been spun from a spin dope containing sulfuric acid, the yarn having a tenacity of 32 cN/dtex (35.6 gpd) or higher; wherein the yarn has not been washed or neutralized with a base that fully dissociates in aqueous solution.
2. The yarn of claim 1 having a tenacity of 34 cN/dtex (37.8 gpd) or higher.
3. The yarn of claim 2 having a tenacity of 36 cN/dtex (40 gpd) or higher.
4. The yarn of claim 1 having a sulfur content of 0.1 to 2.5 percent by weight based on weight of the yarn.
5. The yarn of claim 1 , wherein said copolymer comprises residues of 5(6)-amino-2-(p-aminophenyl)benzimidazole, aromatic diamine, and aromatic diacid-chloride.
6. The yarn of claim 5 , wherein said aromatic diacid-chloride is terephthaloyl dichloride.
7. The yarn of claim 5 , wherein the aromatic diamine is paraphenylenediamine.
8. The yarn of claim 5 , wherein a stoichiometric amount of aromatic diacid-chloride relative to the sum of the amount of 5(6)-amino-2-(p-aminophenyl)benzimidazole and aromatic diamine is utilized in forming the copolymer.
9. The yarn of claim 5 , wherein the molar ratio of 5(6)-amino-2-(p aminophenyl) benzimidazole to aromatic diamine is in the range of from 30/70 to 85/15.
10. The yarn of claim 9 , wherein the molar ratio of 5(6)-amino-2-(p aminophenyl) benzimidazole to aromatic diamine is in the range of from 45/55 to 85/15.