Method for removing sulfur from fiber using a weak base
View Patent ↗The present invention concerns methods for removing sulfur from a fiber comprising the steps of: a) contacting never-dried sulfur-containing fiber in a yarn with an aqueous base having a pKa less than or equal to 11 to release at least a portion of said sulfur, said sulfur comprising, at least in part, sulfate anions and said yarn comprising fiber derived from polymer comprising imidazole groups; and b) rinsing said yarn to remove at least a portion of released sulfur.
1. A method for removing sulfur from a fiber comprising the steps of:
a) contacting never-dried sulfur-containing fiber in a yarn with an aqueous base having a pKa less than or equal to 11 to release at least a portion of said sulfur, said sulfur comprising, at least in part, sulfate anions and said yarn comprising fiber derived from polymer comprising imidazole groups; and
b) rinsing said yarn to remove at least a portion of released sulfur.
2. The method of claim 1 , wherein the aqueous base comprises ammonium hydroxide, sodium bicarbonate, sodium carbonate, or mixtures thereof.
3. The method of claim 1 , wherein said polymer comprises residues of 5(6)-amino-2-(p-aminophenyl)benzimidazole, aromatic diamine, and aromatic diacid-chloride.
4. The method of claim 3 , wherein said aromatic diacid-chloride is terephthaloyl dichloride.
5. The method of claim 3 , wherein said aromatic diamine is para-phenylenediamine.
6. The method of claim 3 , wherein the molar ratio of 5(6)-amino-2-(p-aminophenyl)benzimidazole to aromatic diamine is in the range of from 30/70 to 85/15.
7. The method of claim 6 , wherein the molar ratio of 5(6)-amino-2-(p-aminophenyl)benzimidazole to aromatic diamine is 45/55 to 85/15.
8. The method of claim 1 , wherein in step b) the yarn is rinsed with additional quantities of aqueous base, said aqueous base being the same or different than the base used in step a).
9. The method of claim 1 , wherein in step b) the yarn is rinsed with an aqueous solution.
10. The method of claim 1 , wherein in step b) the yarn is rinsed with water.
11. The method of claim 1 , where after step b), the yarn has a sulfur content of 0.01 to 3 percent, based on the weight of the yarn.
12. The method of claim 11 , where after step b), the yarn has a sulfur content of 0.1 to 2.5 percent, based on the weight of the yarn.
13. The method of claim 11 , where after step b), the yarn has a sulfur content of 0.05 to 1.75 percent, based on the weight of the yarn.
14. The method of claim 13 , where after step b), the yarn has a sulfur content of 0.05 to 1.0 percent, based on the weight of the yarn.
15. The method of claim 11 , where after step b), the yarn has a sulfur content of 0.01 to 0.08 percent, based on the weight of the yarn.
16. The method of claim 15 , where after step b), the yarn has a sulfur content of 0.01 to 0.05 percent, based on the weight of the yarn.
17. The method of claim 1 , further comprising the step of heating the yarn to a temperature of at least 350° C.
18. The method of claim 17 , wherein the yarn after heating has a tenacity of 32 cN/dtex (35.6 gpd) or higher.
19. The method of claim 18 , wherein the yarn after heating has a tenacity of 34 cN/dtex (37.8 gpd) or higher.
20. The method of claim 19 , wherein the yarn after heating has a tenacity of 36 cN/dtex (40 gpd) or higher.