Sulfur and alkali metal containing imidazole fiber having ionically bound halides
View Patent ↗The present invention concerns fiber made from a polymer comprising imidazole groups, the polymer further having: i) halide anions being present in an amount in the range of 0.05 to 20.1 weight percent, based on weight of fiber; ii) sulfur, wherein the sulfur is present in the fiber in an amount in the range of 0.05 to 3 weight percent, based on weight of fiber; and iii) alkali metal ion, wherein the alkali metal ion is present in the fiber in an amount in the range of 0.05 to 2 weight percent, based on weight of fiber.
1. A fiber made from a polymer comprising imidazole groups, the fiber further having:
i) halide anions, the halide anions being present in an amount of 0.05 to 20.1 weight percent, based on weight of fiber, and ionically bound to protonated imidazole groups in the polymer;
ii) sulfur, wherein the sulfur is present in the fiber in an amount of 0.01 to 3 weight percent, based on weight of fiber; and
iii) alkali metal ion, wherein the alkali metal ion is present in the fiber in an amount of 0.05 to 2 weight percent, based on weight of fiber,
wherein the fiber has a yarn tenacity of 32 cN/dtex (35.6 gpd) or higher.
2. The fiber of claim 1 wherein the halide anions are present in an amount of 0.1 to 5 weight percent, based on weight of fiber.
3. The fiber of claim 2 wherein the halide anions are present in an amount of 0.1 to 1 weight percent.
4. The fiber of claim 3 , wherein the halide anions are present in an amount of 0.1 to 0.5 weight percent.
5. The fiber of claim 1 , wherein said polymer comprises residues of 5(6)-amino-2-(p-aminophenyl)benzimidazole, aromatic diamine, and aromatic diacid-chloride.
6. The fiber of claim 5 , wherein said aromatic diacid-chloride is terephthaloyl dichloride.
7. The fiber of claim 5 , wherein said aromatic diamine is para-phenylenediamine.
8. The fiber of claim 5 having a molar ratio of 5(6)-amino-2-(p-aminophenyl)benzimidazole to aromatic diamine of from 30/70 to 85/15.
9. The fiber of claim 8 , wherein the molar ratio of 5(6)-amino-2-(p-aminophenyl)benzimidazole to aromatic diamine is 45/55 to 85/15.
10. The fiber of claim 1 , wherein said halide anions comprise one or more of F—, Cl—, Br—, and I—.
11. The fiber of claim 10 , wherein said halide anions comprise one or more of Cl— and Br—.
12. The fiber of claim 1 , wherein said alkali metal ion is sodium, potassium, or lithium.
13. The fiber of claim 12 , wherein said alkali metal ion is sodium.
14. The fiber of claim 1 having a sulfur content of 0.1 to 2.5 percent by weight based on the weight of the fiber.
15. The fiber of claim 1 having a sulfur content of 0.05 to 1.75 percent by weight based on weight of the fiber.
16. The fiber of claim 15 having a sulfur content of 0.05 to 1 percent by weight based on weight of the fiber.
17. A yarn comprising fiber of claim 1 .
18. The yarn of claim 17 wherein the yarn tenacity of 34 cN/dtex (37.8 gpd) or higher.
19. The yarn of claim 18 wherein the yarn tenacity of 36 cN/dtex (40 gpd) or higher.
20. Fabric comprising yarn of claim 17 .