COMPACT, LIGHTFAST POLYURETHANE MOULDED PARTS
The invention relates to compact, lightfast polyurethane moulded parts which consist of isocyanates, polyols and chain extenders and/or cross-linking agents, as well as to the use of same.
1 - 11 . (canceled)
12 . A compact, lightfast polyurethane molding with Shore A hardness (measured in accordance with DIN 53505) of at least 70 obtained from
A) an organic isocyanate compound having at least two aliphatically bonded isocyanate groups,
B) a polyol having an average molar mass of from 1000 to 15 000 g/mol and an average functionality of from 1.8 to 8,
C) a polyol and/or polyamine having a molar mass of from 60 to 500 g/mol and having a functionality of from 2 to 8 as chain extenders/crosslinking agents,
D) a catalyst, and
E) optionally, other auxiliaries and additives,
wherein component A) has less than 0.5% by weight content of monomeric diisocyanate, a viscosity (measured in accordance with DIN EN ISO 3219) of at most 30 000 mPas (at 20° C.), and an average NCO functionality of from 2.0 to 3.2.
13 . The compact, lightfast polyurethane molding as claimed in claim 12 , wherein the polyol B) has an average functionality of from 2 to 6.
14 . The compact, lightfast polyurethane molding as claimed in claim 12 , wherein the polyol and/or polyamine C) as chain extenders/crosslinking agents has a functionality of from 2 to 4.
15 . The compact, lightfast polyurethane molding as claimed in claim 12 , wherein component A) has an average NCO functionality of from 2.2 to 3.0.
16 . The compact, lightfast polyurethane molding as claimed in claim 12 , wherein component A) has an average NCO functionality of from 2.2 to <2.5.
17 . The compact, lightfast polyurethane molding as claimed in claim 12 with Shore A hardness (measured in accordance with DIN 53505) of from 75 to 85.
18 . The compact, lightfast polyurethane molding as claimed in claim 12 , wherein the organic isocyanate compounds A) are mixtures of from 35 to 95% by weight of at least one polyisocyanate a-1) produced from at least one linear aliphatic diisocyanate and having an NCO content of from 10 to 28% by weight and of from 5 to 65% by weight of at least one polyisocyanate a-2) produced from at least one cycloaliphatic diisocyanate and having an NCO content of from 10 to 22% by weight, and wherein in the polyisocyanate mixture at least one of the polyisocyanates a-1) and a-2) has an average NCO functionality of ≦2.6 and is present in an amount of at least 30% by weight, based on A).
19 . The compact, lightfast polyurethane molding as claimed in claim 18 , wherein in the polyisocyanate mixture A) at least one of the polyisocyanates a-1) and a-2) has an average functionality of ≦2.5.
20 . The compact, lightfast polyurethane molding as claimed in claim 18 , wherein in the polyisocyanate mixture A) at least one of the polyisocyanates a-1) and a-2) has an average functionality of ≦2.4.
21 . A method comprising utilizing the molding as claimed in claim 12 as cladding for dashboards and consoles, as cladding of doors and parcel shelves in the vehicle sector, as materials surrounding automobile windows, materials surrounding other windows, materials surrounding solar modules, materials surrounding worktop edges, materials surrounding metal supports and metal inserts.
22 . A process for the production of the molding as claimed in claim 12 by a RIM (Reaction Injection Molding) process or by direct application of the mixture of components A) to E) to a support made of a polycarbonate, of a polycarbonate blend, of an aromatic polyurethane, or of an injection-molding plastic in the direct skinning process.