Radiation curable (meth)acrylated compounds

1. A radiation curable composition comprising:

a) at least one (meth)acrylated compound (A) prepared from: (i) a polyol constituent, (ii) a polyacid constituent and (iii) one or more (meth)acrylating compounds, wherein the polyol constituent comprises, relative to the total weight of the polyol constituent, at least 30% by weight of one or more dianhydrohexitols, and wherein the compound (A) optionally further contains one or more moieties selected from the group consisting of (poly)caprolactone-containing moieties (ai), (poly)lactide- and/or (poly)glycolide-containing moieties (aii), moieties providing epoxide groups (aiii) and moieties providing alkylene oxide groups containing from 2 to 4 carbon atoms (aiv), and

b) at least one compound (B3) represented by the general formula (VI):

Y—X(A) n′ —Y′

wherein:

Y and Y′ independently are the residues of a (meth)acrylating compound;

X is the residue of a dianhydrohexitol;

A represents a residue of a (poly)caprolactone, a (poly)lactide, a (poly)glycolide, a compound providing epoxide groups, and/or of an alkylene oxide group containing from 2 to 4 carbon atoms; and

n′ is an integer from 0 to 10.

2. The radiation curable composition of claim 1 , wherein the polyol constituent comprises from 40 to 100% by weight of dianhydrohexitols and, optionally, from 0 to 60% by weight of one or more polyols that are different from cyclic ether polyols.

3. The radiation curable composition of claim 1 , wherein the dianhydrohexitol is isosorbide.

4. The radiation curable composition of claim 1 , wherein the (meth)acrylating compounds (iii) are attached to the molecule's backbone via ester groups and/or via carbamate groups.

5. The radiation curable composition of claim 1 , wherein the at least one (meth)acrylated comound (A) is represented by the general formula (I):

Y-[Polyol(A) n -Polyacid] m -X(A) n′ -Y′

wherein:

Y and Y′ independently are the residues of a (meth)acrylating compound;

X is the residue of a dianhydrohexitol;

A represents the residue of a (poly)caprolactone, a (poly)lactide, a (poly)glycolide, a compound providing epoxide groups, or of an alkylene oxide group containing from 2 to 4 carbon atoms;

n and n′ independently are integers from 0 to 10; and

m is an integer from 1 to 5.

6. The radiation curable composition of claim 5 , wherein the (meth)acrylating compounds are selected from: an unsaturated acid, an acyl halide of the unsaturated acid, and/or a C 1 -C 4 alkyl ester of the unsaturated acid.

7. The radiation curable composition of claim 5 , wherein the (meth)acrylating compound (iii) is (meth)acrylic acid.

8. The radiation curable composition of claim 5 , wherein the (meth)acrylating compound (iii) is the reaction product of at least one polyisocyanate (iv) and at least one compound (v) containing at least one reactive group capable to react with isocyanate groups as well as at least one (meth)acryloyl group.

9. The radiation curable composition of claim 1 comprising at least 5% by weight of at least one compound (A).

10. The radiation curable composition of claim 1 , further comprising at least one compound (B1) selected from polyester (meth)acrylates, epoxy (meth)acrylates, urethane (meth)acrylates and/or acrylic copolymers.

11. The radiation curable composition of claim 1 further comprising at least one photo-initiator.

12. The radiation curable composition of claim 1 which is a hard coat composition that after curing has a Persoz hardness of at least 300 sec as measured at 25° C. on 40μ films on glass.

13. The radiation curable composition of claim 1 which is an ink.

14. An article or substrate, having applied to a least one of its surfaces the radiation curable composition of claim 1 .

15. The radiation curable composition of claim 1 , wherein n′ is 0.

16. The radiation curable composition of claim 11 , wherein the photo-initiator is a polymeric photo-initiator (B2).