Weather resistant polyoxymethylene compositions
View Patent ↗The present invention relates to a composition comprising a) at least one polyoxymethylene (A) having terminal OH-groups of more than 15 mmol/kg, b) at least one coupling agent (B), c) one or more hindered amine light stabilizer (C) having a molecular weight ranging from 500 to 1000 g/mol, and d) optionally at least one reinforcing fiber (D).
1. A composition comprising
a) at least one polyoxymethylene (A) having terminal OH-groups of more than 20 mmol/kg, the at least one polyoxymethylene being present in the composition in an amount ranging from 55 wt. % up to 95 wt. %,
b) at least one coupling agent (B) comprising a polyisocyanate,
c) one or more hindered amine light stabilizer(s) (C) having a molecular weight ranging from 500 to 1000 g/mol, and
d) optionally at least one reinforcing fiber (D).
2. A composition according to claim 1 , wherein at least 50%, of the terminal groups of the at least one polyoxymethylene (A) are hydroxyl groups.
3. A composition according to claim 1 , wherein the at least one coupling agent (B) is an organic diisocyanate.
4. A molding composition according to claim 1 , wherein the at least one polyoxymethylene (A) has a MVR ranging from 20 to 100 cm 3 /10 min determined according to ISO 1133 at 190° C. and 2.16 kg.
5. A composition according to claim 1 , wherein the at least one polyoxymethylene (A) has a content of terminal hydroxyl groups of at least 40 mmol/kg.
6. A composition according to claim 1 , wherein the one or more hindered amine light stabilizers (C) has an antioxidant moiety.
7. A composition according to claim 1 , wherein the one or more hindered amine light stabilizers (C) has two or more sterically hindered amine groups.
8. A composition according to claim 1 , wherein the one or more hindered amine light stabilizers (C) comprises at least one tertiary amine moiety.
9. A composition according to claim 1 , wherein the one or more hindered amine light stabilizers (C) has a melting point ranging from 110 to 200° C.
10. A composition according to claim 1 , wherein the one or more hindered amine light stabilizers (C) comprises a di-tert-butyl phenol moiety.
11. A composition according to claim 1 , wherein the one or more hindered amine light stabilizers (C) is Bis(1,2,2,6,6-penta methyl-4-piperidinyl)[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]butylmalonate.
12. Method for producing a molding composition comprising melt mixing the composition as defined in claim 1 .
13. Molded article obtained by molding a composition according to claim 1 .
14. A composition according to claim 1 , wherein the composition contains the at least one reinforcing fiber.
15. A composition according to claim 14 , wherein the at least one reinforcing fiber comprises glass fibers, the glass fibers provided with a sizing, the sizing comprising a silane, the at least one reinforcing fiber being present in the composition in an amount from about 7% by weight to about 45% by weight.
16. A composition comprising
a) a polyoxymethylene polymer having terminal OH-groups of more than 15 mmol/kg, the polyoxymethylene polymer being present in the composition in an amount from about 55 wt % to about 95 wt %;
b) a coupling agent comprising a polyisocyanate;
c) a hindered amine light stabilizer having a molecular weight ranging from 500 to 1,000 g/mol, the hinder amine light stabilizer comprising Bis(1,2,2,6,6-penta methyl-4-piperidinyl)[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]methyl]butylmalonate; and
d) glass fibers being present in the composition in an amount from about 5% by weight to about 50% by weight, the glass fibers including a sizing, the sizing comprising a silane.