Thermoplastic, semiconductive compositions
Crosslinkable, semiconductive, peroxide-free thermoplastic compositions having a stable volume resistivity of less than 1000 ohm-cm comprise, based on the weight of the composition: A. 60-90 wt % silane-functionalized polyethylene; B. 0.5-20 wt % organopolysiloxane containing two or more functional end groups; C. 10-20 wt % high conductivity carbon black, e.g., a carbon black having an average particle size of 50 nm or less, a surface area (BET) of 700-1250 m 2 /g, and an oil absorption (DBP) of 300-500 ml/100 g; and D. 0.05-0.2 wt % crosslinking catalyst.
1. A crosslinkable, semiconductive, peroxide-free thermoplastic composition having a stable volume resistivity of less than 1000 ohm-cm at 90° C. comprising, based on the weight of the composition:
A. 60-90 wt % silane-functionalized polyethylene;
B. 0.5-20 wt % organopolysiloxane containing two or more functional end groups; and
C. 10-20 wt % carbon black having an average particle size of 50 nm or less, a surface area (BET) of 700-1250 m 2 /g, and an oil absorption (DBP) of 300-500 ml/100 g; and
D. 0.05-0.2 wt % crosslinking catalyst.
2. The composition of claim 1 in which the thermoplastic composition has a stable volume resistivity of less than 500 ohm-cm at 90° C.
3. The composition of claim 1 in which the silane-functionalized polyethylene is a silane-functionalized ethylene/α-olefin interpolymer having a α-olefin content of 15 to 50 wt % based on the weight of the interpolymer.
4. The composition of claim 1 in which the silane functionality of the polyethylene comprises at least 0.5 wt % of the total weight of the polyethylene.
5. The composition of claim 1 in which the organopolysiloxane is of the formula R 2 SiO in which each R is independently selected from a group consisting of alkyl radicals comprising one to 12 carbon atoms, alkenyl radicals comprising two to 12 carbon atoms, aryls, and fluorine substituted alkyl radicals comprising one to 12 carbon atoms.
6. A process for making a crosslinked, semiconductive, thermoplastic article having a stable volume resistivity of less than 1000 ohm-cm at 90° C., the process comprising the steps of:
A. Combining a silane-functionalized polyethylene with an organopolysiloxane containing two or more functional end groups to form a crosslinkable compound;
B. Combining under ambient conditions (1) the crosslinkable compound of (A) with, (2) carbon black having an average particle size of 50 nm or less, a surface area (BET) of 700-1250 m 2 /g, and an oil absorption (DBP) of 300-500 ml/100 g, to form a first mixture comprising 80-90 wt % of the crosslinkable compound of (A) and 10-20 wt % of the carbon black, based on the weight of the first mixture;
C. Combining the first mixture with 0.05-0.2 wt % of a crosslinking catalyst to form a homogeneous second mixture;
D. Shaping the second mixture under non-crosslinking conditions into a crosslinkable, semiconductive, thermoplastic article; and
E. Subjecting the shaped, crosslinkable, semiconductive, thermoplastic article to crosslinking conditions.
7. The process of claim 6 comprising the additional step of pelletizing the crosslinkable compound of (A) before mixing it with the organopolysiloxane.
8. The process of claim 6 in which the catalyst is added as a pre-mixed masterbatch.
9. A pellet comprising:
A. 60-90 wt % silane-functionalized polyethylene;
B. 0.5-20 wt % organopolysiloxane containing two or more functional end groups; and
C. 10-20 wt % high conductivity carbon black having an average particle size of 50 nm or less, a surface area (BET) of 700-1250 m 2 /g, and an oil absorption (DBP) of 300-500 ml/100 g.