Anti-vibration rubber composition, crosslinked anti-vibration rubber composition, and anti-vibration rubber
View Patent ↗Provided is a vibration-insulating rubber composition and a crosslinked vibration-insulating rubber composition which are excellent in low dynamic-to-static modulus ratio, elongation fatigue resistance, low temperature characteristics, and processability, and a vibration-insulating rubber using the vibration-insulating rubber composition and the crosslinked vibration-insulating rubber composition. The vibration-insulating rubber composition of the present invention includes: a rubber component having a conjugated diene compound/non-conjugated olefin copolymer, and a non-conjugated diene-based polymer; a vulcanizing agent having a bismaleimide compound; and N-phenyl-N-(trichloromethylthio)benzenesulfonamide.
1. A vibration-insulating rubber composition, comprising:
a rubber component having a conjugated diene compound/non-conjugated olefin copolymer, and a conjugated diene-based polymer;
a vulcanizing agent having a bismaleimide compound; and
N-phenyl-N-(trichloromethylthio)benzenesulfonamide
wherein the conjugated diene compound/non-conjugated olefin copolymer has a cis-1,4 bond content of 50% or more in a moiety derived from a conjugated diene compound.
2. The vibration-insulating rubber composition according to claim 1 , wherein the bismaleimide compound is contained by 1.0 to 5.0 parts by mass per 100 parts by mass of the rubber component, and the N-phenyl-N-(trichloromethylthio)benzenesulfonamide is contained by 0.2 to 4 parts by mass per 100 parts by mass of the rubber component.
3. The vibration-insulating rubber composition according to claim 1 , further comprising sulfur by 0.2 to 1.0 parts by mass per 100 parts by mass of the rubber component.
4. The vibration-insulating rubber composition according to claim 1 , wherein the conjugated diene compound/non-conjugated olefin copolymer has a polystyrene equivalent weight-average molecular weight of 10,000 to 10,000,000.
5. The vibration-insulating rubber composition according to claim 1 , wherein the conjugated diene compound/non-conjugated olefin copolymer has a molecular weight distribution (Mw/Mn) of 10 or less.
6. The vibration-insulating rubber composition according to claim 1 , wherein the conjugated diene compound/non-conjugated olefin copolymer is contained by 10 to 90 parts by mass per 100 parts by mass of the rubber component.
7. The vibration-insulating rubber composition according to claim 1 , wherein the non-conjugated olefin is acyclic olefin.
8. The vibration-insulating rubber composition according to claim 1 , wherein the non-conjugated olefin has 2 to 10 carbon atoms.
9. The vibration-insulating rubber composition according to claim 7 , wherein the non-conjugated olefin is at least one selected from a group consisting of ethylene, propylene, and 1-butene.
10. The vibration-insulating rubber composition according to claim 9 , wherein the non-conjugated olefin is ethylene.
11. The vibration-insulating rubber composition according to claim 1 , wherein the conjugated diene-based polymer is at least one selected from natural rubber, butadiene rubber, styrene-butadiene rubber, and polychloroprene.
12. A crosslinked vibration-insulating rubber composition obtained by crosslinking the vibration-insulating rubber composition according to claim 1 .
13. A vibration-insulating rubber member containing the vibration-insulating rubber composition according to claim 1 .