Method for producing 2,3,3,3-tetrafluoropropene
View Patent ↗The invention concerns a method for producing 2,3,3,3-tetrafluoropropene comprising: a fluoridation reaction of a halopropane and/or halopropene into 2,3,3,3-tetrafluoropropene by means of hydrogen fluoride; the recovery of a gas stream resulting from the reaction; the cooling and partial condensation of the gas stream resulting from the reaction into a partially condensed stream; the separation of the partially condensed stream into a gas fraction and a liquid fraction; the compression of the gas fraction into a compressed gas fraction; the compression of the liquid fraction into a compressed liquid fraction; the distillation of the compressed gas fraction and compressed liquid fraction in order to provide a stream of 2,3,3,3-tetrafluoropropene, a stream of hydrochloric acid, and a stream of unreacted hydrogen fluoride. The invention also concerns an installation suitable for implementing said method.
1. A method for producing 2,3,3,3-tetrafluoropropene, comprising:
reactively fluorinating a halopropane and/or halopropene to 2,3,3,3-tetrafluoropropene using hydrogen fluoride;
recovering a gaseous stream obtained from the reaction;
cooling and partially condensing the gaseous stream obtained from the reaction, to give a partially condensed stream;
separating the partially condensed stream into a gaseous fraction and a liquid fraction;
compressing the gaseous fraction to give a compressed gaseous fraction;
compressing the liquid fraction to give a compressed liquid fraction;
distilling the compressed gaseous fraction and the compressed liquid fraction to give a 2,3,3,3-tetrafluoropropene stream, a hydrochloric acid stream, and a stream of unreacted hydrogen fluoride.
2. The method as claimed in claim 1 , wherein the stream of unreacted hydrogen fluoride further comprises organic compounds.
3. The method as claimed in claim 1 , wherein the stream of unreacted hydrogen fluoride is recycled to the fluorination reaction.
4. The method as claimed in claim 1 , wherein the fluorination reaction is a gas-phase catalytic fluorination reaction.
5. The method as claimed in claim 1 , wherein the fluorination reaction is carried out at a pressure lower than that of the distillation of the compressed gaseous fraction and the compressed liquid fraction.
6. The method as claimed in claim 1 , wherein the fluorination reaction is carried out at a pressure of from 0.1 to 10 bar abs and/or the distillation is carried out at a pressure of from 5 to 40 bar abs.
7. The method as claimed in claim 1 , wherein the gaseous fraction represents from 25% to 60% of the partially condensed stream, and the liquid fraction represents from 40% to 75% of the partially condensed stream, in proportions by mass.
8. The method as claimed in claim 1 , wherein the distillation step comprises:
distilling the compressed gaseous fraction and the compressed liquid fraction in a first distillation;
recovering the stream of unreacted hydrogen fluoride at the end of the first distillation;
recovering an intermediate stream at the end of the first distillation;
distilling the intermediate stream in a second distillation;
recovering the hydrochloric acid stream at the end of the second distillation; and
recovering the 2,3,3,3-tetrafluoropropene stream at the end of the second distillation.
9. The method as claimed in claim 1 , wherein the distillation step comprises:
distilling the compressed gaseous fraction and the compressed liquid fraction in a first distillation;
recovering the hydrochloric acid stream at the end of the first distillation;
recovering an intermediate stream at the end of the first distillation;
distilling the intermediate stream in a second distillation;
recovering the 2,3,3,3-tetrafluoropropene stream at the end of the second distillation; and
recovering the stream of unreacted hydrogen fluoride at the end of the second distillation.
10. The method as claimed in claim 1 , wherein the compressed gaseous fraction and the compressed liquid fraction are introduced at different sites of a distillation column.
11. The method as claimed in claim 1 , wherein the 2,3,3,3-tetrafluoropropene stream undergoes one or more further purification steps.
12. The method as claimed in claim 1 , wherein the halopropane and/or halopropene comprises a chloropropane and/or chloropropene.