Method and device for reducing iron oxide-containing feedstocks
View Patent ↗A method and a device for reducing iron-oxide-containing feedstocks, in which a reducing gas is fed to a reducing unit ( 1 ) containing the iron-oxide-containing feedstocks. The reducing gas is generated by introducing a process gas having reduction potential into a heating appliance ( 3 ) for heating the process gas, which is withdrawn as reducing gas therefrom. In the heating appliance ( 3 ), heat energy is transferred to the process gas. The heat energy is formed by combustion of a fuel gas containing organic substances, including coke oven gas with addition of technically pure oxygen. The flames of the combustion have an adiabatic flame temperature of above 1000° C., wherein, in the combustion of the fuel gas, at least some of the organic substances present in the fuel gas are cracked.
1. A method for reducing iron-oxide-containing feedstocks, comprising:
supplying a reducing gas to a reducing unit containing the iron-oxide-containing feedstocks;
generating the reducing gas by introducing a process gas having reduction potential into a heating appliance, heating the process gas in the heating appliance and withdrawing the process gas as the reducing gas from the heating appliance, during which heat energy is transferred to the process gas; and
forming the heat energy in the heating appliance by combustion of a fuel gas containing coke oven gas having at least some crackable organic substances, while adding technically pure oxygen, such that a flame results from the combustion and the flame has an adiabatic flame temperature greater than 1000° C.;
subjecting the coke oven as to a cleaning process prior to combustion of the coke oven gas in the heating appliance;
wherein the at least some organic substances present in the fuel gas are cracked, and wherein the heat energy is transferred to the process gas in a direct heat exchange by mixing, in the heating appliance, the process gas with the combustion products formed during the combustion of the fuel gas.
2. The method as claimed in claim 1 , further comprising originating the process gas from a CO 2 separating appliance.
3. The method as claimed in claim 1 , wherein the fuel gas comprises at least a partial amount of the process gas.
4. The method as claimed in claim 1 , further comprising subjecting at least a partial amount of the process gas to preheating by heat exchange prior to introduction of the at least partial amount of the process gas into the heating appliance.
5. The method as claimed in claim 1 , further comprising preheating the fuel gas and/or the technically pure oxygen by heat exchange prior to the combustion of the fuel gas in the heating appliance.
6. The method as claimed claim 4 , further comprising preheating the partial amount of the process gas to a temperature greater than 300° C.
7. The method as claimed in claim 1 , further comprising withdrawing the reducing gas from the heating appliance at a temperature of the gas greater than 750° C.
8. The method as claimed in claim 4 , further comprising consuming the reducing gas during the reduction of the iron-oxide-containing feedstocks in the reducing unit and withdrawing the reduction gas as top gas, and the preheating of the partial amount of the process gas is performed by heat exchange with at least a partial amount of the top gas and/or with a residual gas that forms in the CO 2 separating appliance and/or with a mixture of the partial amount of the withdrawn top gas and the residual gas.
9. The method as claimed in claim 1 , further comprising, prior to being supplied to the reducing unit, subjecting the reducing gas withdrawn from the heating appliance to partial combustion with technically pure oxygen and/or the fuel gas.