Fiber grade with improved spinning performance and mechanical properties
The present invention is directed to a new polypropylene composition, polypropylene fibres comprising said polypropylene composition, a spunbonded fabric comprising said polypropylene fibres and/or polypropylene composition, an article comprising said polypropylene fibres and/or said spunbonded fabric as well as to a process for the preparation of such spunbonded fabric and the use of such polypropylene composition for improving the stability of a fibre spinning line.
1. A polypropylene composition (PP-C) comprising:
a) at least 80 wt. %, based on the total weight of the polypropylene composition (PP-C), of a polypropylene (L-PP) homo- or copolymer having a melt flow rate according to ISO 1133 (230° C./2.16 kg) in the range of 0.6 g/10 min to 5 g/10 min and a comonomer content of up to 5 wt. %, the comonomers are selected from ethylene and/or C 4 - to C 10 α-olefin, and
b) between 2 wt. % and 20 wt. %, based on the total weight of the polypropylene composition (PP-C), of a polypropylene (H-PP) homo- or copolymer having a melt flow rate according to ISO 1133 (230° C./2.16 kg) in the range of 800 g/10 min to 1,600 g/10 min and a comonomer content of up to 5 wt. %, the comonomers are selected from ethylene and/or C 4 - to C 10 α-olefin,
wherein the polypropylene composition (PP-C) comprising polypropylene (L-PP) and polypropylene (H-PP) has been visbroken with a visbreaking ratio [final MFR2 (230° C.)/initial MFR2 (230° C.)] of 9 to 50, wherein “final MFR2 (230° C.)” is the MFR2 (230° C.) of the polypropylene composition (PP-C) after visbreaking and “initial MFR2 (230° C.)” is the MFR2 (230° C.) of the polypropylene composition (PP-C) before visbreaking, and
wherein the polypropylene composition (PP-C) has a final melt flow rate according to ISO 1133 (230° C./2.16 kg) in the range of 10 g/10 min to 60 g/10 min and a final polydispersity index (PI) of not more than 4.0.
2. The polypropylene composition (PP-C) according to claim 1 , wherein the polypropylene (L-PP) has:
a) a melt flow rate according to ISO 1133 (230° C./2.16 kg) in the range of 0.7 g/10 min to 3.0 g/10 min, and/or
b) a melting temperature Tm measured according to ISO 11357-3 of at least 150° C., and/or
c) a xylene cold soluble content (XCS) measured according to ISO 6427 (23° C.) of not more than 3.5 wt. %.
3. The polypropylene composition (PP-C) according to claim 1 , wherein the polypropylene (H-PP) has:
a xylene cold soluble content (XCS) measured according to ISO 6427 (23° C.) of not more than 3.5 wt. %.
4. The polypropylene composition (PP-C) according to any one of claim 1 , wherein:
a) the polypropylene (L-PP) is a propylene homopolymer (HL-PP), and/or
b) the polypropylene (H-PP) is a propylene homopolymer (HH-PP).
5. The polypropylene composition (PP-C) according to claim 1 , wherein the polypropylene composition (PP-C) comprises:
a) at least 90 wt. % of polypropylene (L-PP), and
b) between 3 wt. % and 10 wt. % of polypropylene (H-PP), based on the total weight of the polypropylene composition (PP-C), optionally based on the total amount of the polypropylene (L-PP) and the polypropylene (H-PP) together.
6. The polypropylene composition (PP-C) according to claim 1 , wherein the polypropylene composition (PP-C) has:
a) a final melt flow rate according to ISO 1133 (230° C./2.16 kg) in the range of 25 g/10 min to 40 g/10 min, and/or
b) a final polydispersity index (PI) in the range of 2.0 to 4.0.
7. The polypropylene composition (PP-C) according to claim 1 , wherein the polypropylene composition (PP-C) has a ratio of polydispersity index (PI) [initial PI/final PI] of at least 1.3, wherein “final PI” is the polydispersity index (PI) of the polypropylene composition (PP-C) after visbreaking and “initial PI” is the polydispersity index (PI) of the polypropylene composition (PP-C) before visbreaking.
8. Polypropylene fiber (PP-F) having an average filament fineness of not more than 1.50 denier, wherein said fiber (PP-F) comprises at least 95 wt. %, based on the total weight of the polypropylene fiber (PP-F), of a polypropylene composition (PP-C) as defined in claim 1 .
9. The polypropylene fibers (PP-F) according to claim 8 being spunbound into a fabric.
10. The polypropylene fibre (PP-F) according to claim 8 being provided in an article is selected from the group consisting of filtration medium, diaper, sanitary napkin, panty liner, incontinence product for adults, protective clothing, surgical drape, surgical gown, and surgical wear.
11. Process for the preparation of a spunbonded fabric comprising: spunbonding a polypropylene composition (PP-C) by using a fibre spinning line at a maximum cabin air pressure of at least 3,000 Pa, wherein the polypropylene composition (PP-C) includes:
a) at least 80 wt. %, based on the total weight of the polypropylene composition (PP-C), of a polypropylene (L-PP) homo- or copolymer having a melt flow rate according to ISO 1133 (230° C/2.16 kg) in the range of 0.6 g/10 min to 5 g/10 min and a comonomer content of up to 5 wt. %, the comonomers are selected from ethylene and/or C 4 - to C 10 α-olefin, and
b) between 2 wt. % and 20 wt. %, based on the total weight of the polypropylene composition (PP-C), of a polypropylene (H-PP) homo- or copolymer having a melt flow rate according to ISO 1133 (230° C/2.16 kg) in the range of 800 g/10 min to 1,600 g/10 min and a comonomer content of up to 5 wt. %, the comonomers are selected from ethylene and/or C 4 - to C 10 α-olefin,
visbreaking the polypropylene composition (PP-C) comprising polypropylene (L-PP) and polypropylene (H-PP) with a visbreaking ratio [final MFR2 (230° C.)/initial MFR2 (230° C.)] of 9 to 50, wherein “final MFR2 (230° C.)” is the MFR2 (230° C.) of the polypropylene composition (PP-C) after visbreaking and “initial MFR2 (230° C.)” is the MFR2 (230° C.) of the polypropylene composition (PP-C) before visbreaking, and
wherein the polypropylene composition (PP-C) has a final melt flow rate according to ISO 1133 (230° C/2.16 kg) in the range of 10 g/10 min to 60 g/10 min and a final polydispersity index (PI) of not more than 4.0.
12. The process according to claim 11 , wherein the fibre spinning line comprises the following steps of:
a) feeding the polypropylene composition (PP-C) into an extruder to melt the polypropylene composition (PP-C),
b) forcing the molten polypropylene composition (PP-C) through a spinneret having holes of 0.4 mm to 0.7 mm diameter and 65 to 75 holes per cm at a rate of 0.3 g to 1 g per hole per meter to form polypropylene fibres (PP-F), and
c) quenching and drawing the polypropylene fibers (PP-F) at filament speeds of at least 3800 m/min.