IP Library Patent Application 14379559
Patent Application
App. No. 14/379,559

MULTILAYER STRUCTURE AS REFLECTOR WITH INCREASED MECHANICAL STABILITY

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Patent No.
US None
App. No.
14/379,559
Abstract

The present invention relates to a multilayer structure as a reflector with increased mechanical stability, which comprises a substrate layer A, a barrier layer B, a metallic reflector layer C, an optional layer D, a plasma polymer layer E, and a covering layer comprising inorganic constituents, and the covering layer does not contain UV absorber.

Claims (32)

1 . A multilayer structure comprising

layer A: a substrate layer selected from a thermoplastic plastic, metal or glass,

layer B: a barrier layer selected from titanium or the group of the noble metals,

layer C: metallic reflector layer,

layer D: optionally an oxidic layer selected from aluminium oxide (AlOx), titanium dioxide, SiO 2 , Ta 2 O 5 , ZrO 2 , Nb 2 O 5 and HfO,

layer E:

a) is a plasma polymer layer (anticorrosion layer) deposited from siloxane precursors

or

in the case where layer D is aluminium oxide or SiO 2 , layer E is

b) a highly refractive metal oxide layer, the metal oxides being selected from titanium dioxide, SiO 2 , Ta 2 O 5 , ZrO 2 , Nb 2 O 5 and HfO, or can be SiO 2 , and a further layer according to layer E (a), a plasma polymer layer, can optionally be applied,

layer F:

a covering layer comprising inorganic constituents, this layer F not containing UV absorber.

2 . Multilayer structure according to claim 1 , wherein the thermoplastic plastic is selected from at least one of the group consisting of polycarbonate, polystyrene, styrene copolymers, aromatic polyesters, cyclic polyolefins, poly- or copoly-acrylates and poly- or copoly-methacrylate, copolymers with styrene, thermoplastic polyurethanes, polymers based on cyclic olefins, polycarbonate blends with olefinic copolymers or graft polymers.

3 . Multilayer structure according to claim 1 , wherein layer B is of titanium.

4 . Multilayer structure according to claim 1 , wherein layer C is of silver or silver alloys, wherein the silver alloy comprises amounts of less than 10 wt. % gold, platinum, palladium and/or titanium, as well as aluminium.

5 . Multilayer structure according to claim 4 , wherein layer C is of silver.

6 . Multilayer structure according to claim 1 , wherein layer D is of aluminium oxide (AlOx) or titanium dioxide.

7 . Multilayer structure according to claim 1 , wherein layer E is hexamethyldisiloxane.

8 . Multilayer structure according to claim 1 , wherein the layer thicknesses of the layers are as follows:

total thickness of layer A: from 1 μm to 10 mm in the case of thermoplastics, from 300 μm to 750 μm in the case of metallic substrates, from 750 μm to 3 mm in the case of glass,

layer B: from 40 nm to 250 nm,

layer C: from 80 nm to 250 nm,

layer D: from 80 nm to 250 nm,

layer E: from 1 nm to 200 nm,

layer F: from 1 μm to 20 μm.

9 . Multilayer structure according to claim 1 , wherein layer F is sol-gel lacquers which are prepared by hydrolysis of aqueous dispersions of colloidal silicon dioxide and an organoalkoxysilane and/or an alkoxysilane or mixtures of organoalkoxysilanes of the general formula RSi(OR′)3 and/or alkoxysilanes of the general formula Si(OR′)4, wherein in the organoalkoxysilane(s) of the general formula RSi(OR′)3 R represents a monovalent C1- to C6-alkyl radical or a wholly or partially fluorinated C1-C6-alkyl radical, a vinyl unit or an allyl unit, an aryl radical or a C1-C6-alkoxy group.

10 . Multilayer structure according to claim 1 , wherein the layer thickness of layer B is from 80 to 130 nm.

11 . Multilayer structure according to claim 1 , wherein the layer thickness of layer C is from 90 nm to 160 nm, the layer thickness of layer D is from 90 nm to 160 nm, and the layer thickness of layer E is from 20 nm to 100 nm.

12 . Multilayer structure according to claim 1 , wherein the thermoplastic is selected from the group consisting of polycarbonate, aromatic polyesters and polycarbonate blends, wherein these thermoplastics can comprise fillers.

13 . A method comprising utilizing the multilayer structure according to claim 1 as a reflector in photovoltaic modules, solar modules, in lighting systems, as a mirror in the residential field as well as in the automotive field, as a reflector in fibre-optic systems.

14 . Photovoltaic modules, solar modules, lighting systems, fibre-optic systems comprising a multilayer structure according to claim 1 .

15 . Mirror comprising a multilayer structure according to claim 1 .

Assignments (2)
CHANGE OF NAME Recorded Apr 5, 2016
From: BAYER MATERIALSCIENCE AG
To: COVESTRO DEUTSCHLAND AG
Reel/Frame 038358/0387 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 19, 2014
From: OSER, RAFAEL; KUHLMANN, TIMO
To: BAYER MATERIALSCIENCE AG
Reel/Frame 033561/0353 →