IP Library Granted Patent US 9,416,207
Granted Patent B2
US 9,416,207 · App. 14/380,000 · Granted Aug 16, 2016

Polypropylene composition combining softness, toughness, low haze and high thermal resistance

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Quick Facts
Patent No.
US 9,416,207
App. No.
14/380,000
Granted
Aug 16, 2016
Kind
B2
Abstract

The present invention relates to a polypropylene composition comprising comonomer units derived from ethylene in an amount of from 1.5 wt % to 35 wt %, and from at least one C 5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles XS of at least 40 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %.

Claims (23)

1. A polypropylene composition comprising comonomer units derived from ethylene in an amount of from 1.5 wt % to 35 wt % and from at least one C 5-12 alpha-olefin in an amount of from 1.0 mol % to 3.0 mol %, wherein the polypropylene composition has an amount of xylene solubles (XS) of at least 40 wt %, and the xylene solubles have an amount of ethylene-derived comonomer units of from 4.0 wt % to 70 wt %, and wherein the polypropylene composition is a blend comprising propylene polymer fractions P 1 , P 2 and P 3 , wherein

P 1 is a propylene homopolymer or a propylene copolymer comprising comonomer units derived from at least one C 5-12 alpha-olefin in an amount less than 1.0 mol %.

P 2 is a propylene copolymer comprising comonomer units derived from at least one C 5-12 alpha-olefin in an amount of from 2.0 mol % to 7.0 mol %, and

P 3 is a propylene comprising ethylene-derived comonomer derived units in an amount of from 4.0 wt % to 70 wt %; and

wherein each of the propylene polymer fractions P 1 and P 2 contains 0 to less than 1.0 wt % of ethylene-derived comonomer units, and P 3 contains comonomer units derived from at least one C 5-12 alpha-olefin of from 0 to less than 2.0 mol %.

2. The polypropylene composition according to claim 1 , wherein the at least one C 5-12 alpha-olefin is selected from 1-hexene, 1-octene, or any mixture thereof.

3. The polypropylene composition according to claim 1 , wherein the following relation is satisfied:

[ C 2( XS )× XS/ 100]/ C 2(total)≧0.9

wherein

C2(XS) is the amount in wt % of the ethylene-derived comonomer units in the xylene solubles,

XS is the amount in wt % of xylene solubles of the polypropylene composition, and

C2 (total) is the amount in wt % of the ethylene-derived comonomer units in the polypropylene composition.

4. The polypropylene composition according to claim 1 , wherein the xylene solubles contain an amount of comonomer units which are derived from the least one C 5-12 alpha-olefin of from 0.01 mol % to 2.0 mol %.

5. The polypropylene composition according to claim 1 , wherein the total amount of comonomer units derived from ethylene and at least one C 5-12 alpha-olefin in the polypropylene composition is from 3.0 mol % to 48 mol %.

6. The polypropylene composition according to claim 1 , which has a tensile modulus of less 450 MPa.

7. A moulded article, comprising the polypropylene composition according to claim 1 .

8. A process for preparing the polypropylene composition according to claim 1 , comprising:

(i) preparing as a first propylene polymer fraction a propylene homopolymer or a propylene copolymer comprising comonomer units derived from at least one C 5-12 alpha-olefin in a first polymerization reactor PR 1 ,

(ii) transferring the first propylene polymer fraction obtained in the first polymerization reactor PR 1 to a second polymerization reactor PR 2 and preparing a second propylene polymer fraction by polymerizing propylene and at least one C 5-12 alpha-olefin in the presence of the first propylene polymer fraction, thereby obtaining a reactor blend of the first and second propylene polymer fractions,

(iii) transferring the reactor blend of step (ii) into a third polymerization reactor PR 3 and preparing a third propylene polymer fraction by polymerizing propylene and ethylene in the presence of the reactor blend of step (ii), thereby obtaining a reactor blend of the first, second and third propylene polymer fractions.

9. The process according to claim 8 , wherein the split between the first propylene polymer fraction of PR 1 and the second propylene polymer fraction of PR 2 is 70/30 to 30/70 and/or wherein the split between the reactor blend of step (ii) and the third propylene polymer fraction of PR 3 is 60/40 to 40/60.

10. The process according to claim 8 , wherein the first polymerization reactor PR 1 is a slurry reactor and the second and third polymerization reactors are both gas phase reactors.

11. The process according to claim 8 , wherein a single site catalyst is used in at least one of the polymerization reactors PR 1 to PR 3 .

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 13, 2014
From: REICHELT, KRISTIN; HAKOLA, SAMELI; RESCONI, LUIGI
To: BOREALIS AG
Reel/Frame 033936/0877 →