PROCESS FOR THE PRODUCTION OF LOW STRESS AND OPTICAL QUALITY FILM FOR USE IN OPTO-ELECTRONIC DEVICES
The present invention relates to a film with low an optical retardation and thus low stress birefringence which contains at least one layer containing at least one polycarbonate or co-polycarbonate and which, on account of its optical properties, is suitable for use in opto-electronic devices, e.g. in displays and touch panels, as well as to a process for the production of such films and to the use thereof.
1 . Coated film comprising a base film comprising at least one layer comprising at least one poly- or copolycarbonate, wherein the base film has
an optical retardation of less than 100 nm and
a matte side having a surface roughness of from 200 nm to 20 μm and
another side having a surface roughness of less than 200 nm and
a coating on the matte side whereby a surface of said coating has a surface roughness of less than 200 nm.
2 . Coated film according to claim 1 , wherein the coating comprises nanoparticles.
3 . Coated film according to claim 1 , wherein the difference of the refractive indices of the base film and the coating at a wavelength of 550 nm is less than 0.04, optionally by 0.02, or optionally by 0.015.
4 . Coated film according to claim 1 , wherein the base film has an optical retardation of less than 50 nm, optionally of less than 10 nm
5 . Coated film according to claim 1 , wherein the poly- or copolycarbonate in the base film has a glass transition temperature T g of equal to or more than 140° C., optionally of more than 175° C.
6 . Coated film according to claim 1 , wherein poly- or copolycarbonate containing units prepared from one or more dihydroxydiphenylcycloalkanes of formula (Ia) as dihydroxyaryl
compounds comprises
wherein
R 1 and R 2 independently of one another represent hydrogen, halogen, optionally chlorine or bromine, C 1 -C 8 -alkyl, C 5 -C 6 -cycloalkyl, C 6 -C 10 aryl, optionally phenyl, and C 7 -C 12 -aralkyl, optionally phenyl-C 1 -C 4 -alkyl, optionally benzyl,
m represents an integer from 4 to 7, optionally 4 or 5,
R 3 and R 4 , which can be chosen individually for each X, independently of one another represent hydrogen or C 1 -C 6 -alkyl and
X represents carbon,
with the proviso that, on at least one atom X, optionally on one or two atom(s) X, optionally on only one atom X, R 3 and R 4 simultaneously represent alkyl.
7 . Coated film according to claim 6 , wherein
the units prepared from one or more dihydroxydiphenylcycloalkanes of formula (Ia) are units prepared from one or more dihydroxydiphenylcycloalkanes of formula (Ia-1) to (Ia-3)
wherein R 1 and R 2 independently of one another represent hydrogen, halogen, optionally chlorine or bromine, C 1 -C 8 -alkyl, C 5 -C 6 -cycloalkyl, C 6 -C 10 -aryl, optionally phenyl, and C 7 -C 12 -aralkyl, optionally phenyl-C 1 -C 4 -alkyl, optionally benzyl, optionally hydrogen.
8 . Coated film according to claim 6 , wherein the poly- or copoly-carbonate containing units prepared from one or more dihydroxydiphenylcycloalkanes of formula (Ia) is a poly- or copoly-carbonate containing units prepared from 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane, optionally a copolycarbonate containing units prepared from 1,1-bis-(4-hydroxyphenyl)-3,3,5-trimethyl-cyclohexane as dihydroxydiphenylcycloalkanes of formula (Ia) and 2,2-bis-(4-hydroxyphenyl)-propane as a further dihydroxyaryl compound.
9 . Coated film according to claim 1 , wherein the coating is a coating produced from a radiation-curable coating composition comprising nanoparticles, optionally from an acrylate-based radiation-curable coating composition containing nanoparticles.
10 . Process for producing a coated film according to claim 1 , comprising
producing a base film having at least one layer containing at least one poly- or copoly-carbonate, the base film having an optical retardation of less than 100 nm, a matte side having a surface roughness of from 200 nm to 20 μm and another side having a surface roughness of less than 200 nm by extrusion or co-extrusion by extruding or co-extruding a plastics melt and then calendering said melt between two rollers, of which one roller has a steel surface and the other roller has an elastic surface,
coating the base film so produced on the matte side with a coating composition and the coating having a roughness of less than 200 nm after drying and optional additional curing.
11 . Process according to claim 10 , wherein coating is carried out using a radiation-curable coating composition comprising nanoparticles, optionally a radiation-curable coating composition comprising one or more acrylates, wherein curing by radiation is further carried out after application of the coating composition and drying.
12 . Process according to claim 10 , wherein the roller having an elastic surface is a roller having a rubber surface.
13 . A coated film according to claim 1 capable of being used in an opto-electronic device.
14 . A coated film according to claim 1 capable of being used in one or more displays and/or touch panels.
15 . Opto-electronic device, optionally a display or touch panel, comprising at least one coated film according to claim 1 .