Method for producing acrylonitrile
View Patent ↗The invention relates to a method for producing acrylonitrile which includes a vapor phase catalytic ammoxidation process of performing vapor phase catalytic ammoxidation by bringing a source gas containing propylene, molecular oxygen, and ammonia into contact with a fluidized bed catalyst to obtain acrylonitrile. The method is characterized in that the fluidized bed catalyst is a catalyst containing molybdenum and bismuth and the vapor phase catalytic ammoxidation process is performed while maintaining an adsorbed amount of ammonia per specific surface area (m 2 /g) of the fluidized bed catalyst in the range of 0.05 to 0.6 μmol/m 2 . According to the method for producing acrylonitrile of the invention, it is possible to stably maintain a high acrylonitrile yield over a long period of time.
1. A method for producing acrylonitrile, the method comprising
performing vapor phase catalytic ammoxidation by bringing a source gas comprising propylene, molecular oxygen, and ammonia into contact with a fluidized bed catalyst thereby obtaining acrylonitrile,
wherein the fluidized bed catalyst comprises molybdenum and bismuth, and
the vapor phase catalytic ammoxidation is performed while maintaining an adsorbed amount of ammonia per specific surface area (m 2 /g) of the fluidized bed catalyst in the range of from 0.05 to 0.6 μmol/m 2 throughout the entire vapor phase catalytic ammoxidation,
wherein the adsorbed amount of ammonia per specific surface area (m 2 /g) of the fluidized bed catalyst in the range of from 0.05 to 0.6 μmol/m 2 is maintained by increasing or decreasing the ammonia adsorption amount,
and wherein
the increasing of the amount of ammonia adsorbed is performed by adding a compound comprising an element which exhibits acidity in order to promote the adsorption of ammonia, and
the decreasing of the amount of ammonia adsorbed is performed by adding a compound comprising an element which exhibits basicity in order to inhibit the adsorption of ammonia.
2. The method for producing acrylonitrile according to claim 1 , wherein the fluidized bed catalyst is represented by Formula (1):
Mo 12 Bi a Fe b A c D d E e G f O x (SiO 2 ) y (1)
wherein in Formula (1), Mo, Bi, Fe, O, and SiO 2 represent molybdenum, bismuth, iron, oxygen, and silica, respectively,
A represents at least one element selected from the group consisting of nickel, cobalt, zinc, magnesium, manganese, and copper,
D represents at least one element selected from the group consisting of lanthanum, cerium, praseodymium, neodymium, and samarium,
E represents at least one element selected from the group consisting of lithium, sodium, potassium, rubidium, and cesium,
G represents at least one element selected from the group consisting of calcium, strontium, barium, cadmium, titanium, zirconium, vanadium, niobium, tantalum, chromium, tungsten, germanium, tin, yttrium, aluminum, gallium, ruthenium, rhodium, palladium, rhenium, osmium, iridium, platinum, silver, boron, phosphorus, antimony, and tellurium, and
a, b, c, d, e, f, x, and y represent an atomic ratio, and a is from 0.1 to 5, b is from 0.1 to 10, c is from 2 to 12, d is from 0.01 to 5, e is from 0.01 to 2, f is from 0 to 10, y is from 20 to 200, and x is the number of oxygen atom required to satisfy the valence of each of the components except silica with the proviso that c, d, e and f represent a sum of an atomic ratio of each element in a case in which A, D, E and G contain two or more elements.
3. The method according to claim 1 , wherein the vapor phase catalytic ammoxidation is done at a temperature of from 350 to 500° C.
4. The method according to claim 1 , wherein the vapor phase catalytic ammoxidation is done at a pressure of from 100 to 500 kPa.
5. The method according to claim 1 , wherein the source gas has a mole ratio of propylene:ammonia:oxygen in the range of from 1:1 to 2:1 to 5.0.