Organic electroluminescent element

1. An organic electroluminescent device, comprising an anode, a plurality of organic layers including a phosphorescent light-emitting layer, and a cathode laminated on a substrate, wherein at least one of the plurality of organic layers, which is selected from the group consisting of the phosphorescent light-emitting layer, a hole-transporting layer, an electron-transporting layer, and a hole-blocking layer, contains an indolocarbazole compound represented by the general formula (1):

wherein,

a ring I represents an aromatic hydrocarbon ring represented by the formula (1a) to be fused to adjacent rings at arbitrary positions, and a ring II represents a heterocycle represented by the formula (1b) to be fused to adjacent rings at arbitrary positions;

As each represent C—R or N and at least one of As represents N; and

Ls each independently represent a substituted or unsubstituted aromatic hydrocarbon group having 6 to 18 carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 3 to 17 carbon atoms, r represents an integer of 2 or 3, and at least one of Ls represents a monovalent aromatic heterocyclic group represented by the following formula (4);

wherein, Ys each independently represent methine, substituted methine, or nitrogen, and one of Ys represents a carbon atom providing a monovalent group, Qs each independently represent any one of a single bond, —S—, and —O—, and at least one of Ys and Qs represents a heteroatom;

in the general formula (1) and the formula (1a), Rs each independently represent an aliphatic hydrocarbon group having 1 to 10 carbon atoms, an aromatic hydrocarbon group having 6 to 18 carbon atoms, or an aromatic heterocyclic group having 3 to 17 carbon atoms, ps each independently represent an integer of from 0 to 4, and q represents an integer of from 0 to 2;

in the formula (1b), X 1 to X 4 each independently represent an aromatic hydrocarbon group having 6 to 18 carbon atoms or an aromatic heterocyclic group having 3 to 17 carbon atoms, l, m, and n each independently represent an integer of from 0 to 5, and when l, m, or n represents 2 or more, X 2 s, X 3 s, or X 4 s may be identical to or different from each other, and a total number of X 1 to X 4 in the formula (1b) is from 4 to 7.

2. An organic electroluminescent device according to claim 1 , wherein at least one of Ls in the general formula (1) represents a substituted or unsubstituted dibenzofuranyl or dibenzothiophenyl group.

3. An organic electroluminescent device according to claim 1 , wherein the total number of X 1 to X 4 in the formula (1b) is from 5 to 7.

4. An organic electroluminescent device according to claim 1 , wherein the organic layer containing the indolocarbazole compound represented by the general formula (1) comprises a light-emitting layer containing a phosphorescent light-emitting dopant.

5. An organic electroluminescent device according to claim 2 , wherein the organic layer containing the indolocarbazole compound represented by the general formula (1) comprises a light-emitting layer containing a phosphorescent light-emitting dopant.

6. An organic electroluminescent device according to claim 3 , wherein the organic layer containing the indolocarbazole compound represented by the general formula (1) comprises a light-emitting layer containing a phosphorescent light-emitting dopant.

7. An organic electroluminescent device according to claim 2 , wherein the total number of X 1 to X 4 in the formula (1b) is from 5 to 7.

8. An organic electroluminescent device according to claim 1 , wherein, in the formula (1b), the group of:

—X 1 X 2 {—X 3 X 4 ) l } m ] n

is a group produced by removing hydrogen from an aromatic ring selected from the group consisting of benzene, pentalene, indene, naphthalene, anthracene, phenanthrene, pyrrole, imidazole, pyrazole, thiazole, thiophene, pyridine, pyrazine, pyrimidine, pyridazine, triazine, isoindole, indazole, purine, benzimidazole, indolizine, chromene, benzoxazole, isobenzofuran, quinolizine, isoquinoline, imidazole, naphthyridine, phthalazine, quinazoline, quinoxaline, cinnoline, quinoline, pteridine, perimidine, phenanthroline, phenanthridine, acridine, phenazine, phenothiazine, phenoxazine, phenazasiline, dibenzodioxin, carboline, indole, indoloindole, carbazole, furan, benzofuran, isobenzofuran, benzothiazole, oxanthrene, dibenzofuran, thiophene, thioxanthene, thianthrene, phenoxathiin, thionaphthene, isothianaphthene, thiophthene, thiophanthrene, and dibenzothiophene.

9. An organic electroluminescent device according to claim 1 , wherein, in the formula (1b), the group of:

—X 1 X 2 {—X 3 X 4 ) l } m ] n

is selected from the group consisting of:

where R′ represents an aromatic hydrocarbon group having 6 to 18 carbon atoms or an aromatic heterocyclic group having 3 to 17 carbon atoms.