IP Library Granted Patent US 9,458,083
Granted Patent B2
US 9,458,083 · App. 14/384,273 · Granted Oct 4, 2016

Method for hydrolysing acetone cyanohydrin

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Quick Facts
Patent No.
US 9,458,083
App. No.
14/384,273
Granted
Oct 4, 2016
Kind
B2
Abstract

The present invention relates to a process for hydrolysis of acetone cyanohydrin (ACH) by means of sulphuric acid within the ACH sulpho process for preparation of methacrylic acid (MAA) or methyl methacrylate (MMA).

Claims (15)

1. A process for hydrolysis of acetocyanohydrin, the process comprising:

preparing methyl methacrylate in a loop reactor by using sulphuric acid as a precursor,

wherein

at least one heat exchanger present in the loop reactor is equipped with turbulators,

at least one reaction component is fed into the loop reactor via a metering ring, which is installed externally and immediately upstream of a pump with a pump housing in the loop reactor,

the at least one heat exchanger equipped with turbulators is positioned downstream of a metered addition of sulphuric acid and of acetocyanohydrin in flow direction, and

the turbulators are turbulators with 100-1200 turns/m.

2. The process according to claim 1 , wherein the metering ring is integrated into the pump housing.

3. The process according to claim 1 , wherein corkscrew or piperbrush structures are installed as turbulators into the at least one heat exchanger.

4. The process according to claim 1 , wherein helically wound metal tapes are used on turbulators in the loop reactor.

5. The process according to claim 1 , wherein

the at least one heat exchanger is a shell-and-tube heat exchanger, and

at least 50-70% of tubes of the shell-and-tube heat exchanger are equipped with turbulators.

6. The process according to claim 1 , wherein the turbulators are turbulators with 500-750 turns/m.

7. The process according to claim 1 , wherein the turbulators are turbulators with 300-900 turns/m.

Assignments (3)
CORPORATE ADDRESS CHANGE Recorded Jul 31, 2020
From: ROEHM GMBH
To: ROEHM GMBH
Reel/Frame 053837/0501 →
CHANGE OF NAME Recorded Sep 30, 2019
From: EVONIK RÖHM GMBH
To: RÖHM GMBH
Reel/Frame 050587/0022 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 10, 2014
From: SELBACH, ARNDT; SARTORELLI, LORENZA; PERL, ANDREAS; DEINKEN, JOACHIM; SOHNEMANN, STEFANIE; MNICH, NORBERT; GROEMPING, MATTHIAS; GROPP, UDO; MERTZ, THOMAS
To: EVONIK ROEHM GMBH
Reel/Frame 033711/0637 →