Method of manufacturing thin film polarizer, and thin film polarizer and polarizing plate manufactured using the same
A method of manufacturing a thin film polarizer includes forming a film laminate by allowing a non-oriented polyvinyl alcohol-based film to be bonded to and sandwiched between two or more non-oriented polymer films using attractive force or an adhesive layer, orienting the film laminate so that the polyvinyl alcohol-based film has a thickness of 10 μm or less, and separating the polymer films and the polyvinyl alcohol-based film of the oriented film laminate from each other.
1. A method of manufacturing a thin film polarizer, comprising:
forming a film laminate by allowing a non-oriented polyvinyl alcohol-based film to be bonded to and sandwiched between two or more non-oriented polymer films using attractive force or an adhesive layer;
orienting the film laminate so that the polyvinyl alcohol-based film has a thickness of 10 μm or less; and
separating the polymer films and the polyvinyl alcohol-based film of the oriented film laminate from each other,
wherein adhesion between the polyvinyl alcohol-based film and the polymer film after the orienting of the film laminate is 2N/2 cm or less,
wherein the non-oriented polymer film comprises one or more selected from a group including a high-density polyethylene film, a polyurethane film, a polypropylene film, a polyolefin film, an ester-based film, a low-density polyethylene film, high-density polyethylene and low-density polyethylene coextrusion films, a copolymer resin film containing ethylene vinyl acetate in high-density polyethylene, an acrylic film, a polyethylene terephthalate film, and a polyvinyl alcohol-based film,
wherein the orienting of the film laminate is performed through wet orientation at a temperature of 20° C. to 85° C. at an orientation magnification of 5 to 15 times, and
wherein one or more sheets of thin film polarizer are obtained by separating two or more polymer films and one or more polyvinyl alcohol-based film of the oriented film laminate from each other.
2. The method of claim 1 , wherein the film laminate comprises a first non-oriented polymer film, a first non-oriented polyvinyl alcohol-based film bonded to the first non-oriented polymer film, and a second non-oriented polymer film bonded to the first non-oriented polyvinyl alcohol-based film.
3. The method of claim 1 , wherein the film laminate comprises a first non-oriented polymer film, a first non-oriented polyvinyl alcohol-based film bonded to the first non-oriented polymer film, a second non-oriented polymer film bonded to the first non-oriented polyvinyl alcohol-based film, a second non-oriented polyvinyl alcohol-based film bonded to the second non-oriented polymer film, and a third non-oriented polymer film bonded to the second non-oriented polyvinyl alcohol-based film.
4. The method of claim 1 , wherein the orienting of the film laminate is performed in a boron aqueous solution having a boron concentration ranging from 1 to 5 wt %.
5. The method of claim 1 , further comprising dyeing the non-oriented polyvinyl alcohol-based film with at least one of iodine and a dichroic dye before the orienting of the film laminate.
6. The method of claim 1 , wherein the separating of the polymer film from the polyvinyl alcohol-based film in the oriented film laminate is performed by applying 2N/2 cm or less of peel strength.