Semi-hardened pressure-sensitive adhesive film
Disclosed is a semi-hardened pressure sensitive adhesive film to be used in the semi-hardened state and having excellent printing step absorption properties. The adhesive film according to the present invention contains a radial polymer composition and a cationic polymer composition, and the radial polymer composition is primarily cross-linked to maintain the semi-hardened state. When applied onto a substrate through a printing step, the present invention has excellent step absorption properties and adhesion properties and excellent durability even under high-temperature and high-humidity conditions.
1. A touch panel comprising an adhesive film comprising a semi-cured adhesive composition and a substrate having a print step height from 5 μm to 50 μm,
wherein the semi-cured adhesive composition comprises
a primarily crosslinked radical polymerizable composition comprising a compound having at least one unsaturated double bond and a photopolymerization initiator,
the compound having at least one unsaturated double bond comprises at least one of acrylic monomers and acrylic prepolymers, and
cation polymerizable composition comprising a cation polymerizable compound and a cation polymerization initiator,
wherein the ratio of the radical polymerizable composition to the cation polymerizable composition is 1:1,
wherein the cation polymerizable compound comprises at least one of epoxy resins or vinyl ether resins,
wherein the photopolymerization initiator is activated upon UV irradiation of from 1 mW/cm 2 to 10 mW/cm 2 , and the cation polymerization initiator is activated upon UV irradiation of from 50 mW/cm 2 to 150 mW/cm 2 , and
wherein the cation polymerization initiator comprises at least one of aromatic oxosulfonium ions and aromatic iodonium salts.
2. The touch panel according to claim 1 ,
wherein the radial polymerizable composition is crosslinked by UV irradiation and irradiance from 1 mW/cm 2 to 10 mW/cm 2 .
3. The touch panel according to claim 1 ,
wherein the photopolymerization initiator comprises at least one of acetophenone, benzophenone, Michler's ketone, benzoin, benzylmethylketal, benzoyl benzoate, α-acyloxime ester, and thioxanthone initiators.
4. The touch panel according to claim 1 ,
wherein the adhesive film has an adhesive strength of 100 g/in or more.
5. The touch panel according to claim 1 ,
wherein at least one of the acrylic monomers and acrylic prepolymers is selected from at least one of 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, butoxyethyl acrylate, 1,6-hexanediol diacrylate, neopentyl glycol diacrylate, diethylene glycol diacrylate, polyethylene glycol diacrylate, hydroxypivalic acid ester neopentyl glycol diacrylate, dipentaerythritol hexaacrylate, trimethylolpropane triacrylate, pentaerythritol triacrylate, urethane acrylates, polyester acrylates, epoxy acrylates, melamine acrylates, polyfluoroalkyl acrylates, or silicone acrylates.