Carbon fiber thermoplastic resin prepreg, carbon fiber composite material and producing method
View Patent ↗Provided are a carbon fiber thermoplastic resin prepreg which is a carbon fiber prepreg obtained by impregnating a PAN-based carbon fiber in which the average fiber fineness of a single fiber is 1.0 dtex to 2.4 dtex with a thermoplastic resin, wherein the thermoplastic resin satisfies 20≤(FM/FS)≤40 (where FM: flexural modulus (MPa) of a resin sheet comprising only the thermoplastic resin, and FS: flexural strength (MPa) of the resin sheet), a method for manufacturing the same, and a carbon fiber composite material employing the carbon fiber prepreg.
1. A carbon fiber thermoplastic resin prepreg obtained by a process comprising: impregnating a carbon fiber bundle of plural carbon fibers having an average single fiber fineness of from 1.1 dtex to 2.4 dtex with a thermoplastic resin composition, wherein a single fiber of the carbon fiber in the carbon fiber bundle has plural surface asperity structures extending over 2 μm or more in the fiber longitudinal direction, and the difference of elevation between the peak and the bottom (Rp−v) in a region having a circumferential length of the single fiber of 2000 nm×a length in the fiber axial direction of 2000 nm is in the range of 60 nm to 200 nm.
2. The carbon fiber thermoplastic resin prepreg according to claim 1 , wherein the thermoplastic resin composition is a thermoplastic resin that satisfies Formula (1):
20≤(FM/FS)≤40 (1)
where,
FM represents a flexural modulus (MPa) of a resin plate formed from the thermoplastic resin composition only; and
FS represents a flexural strength (MPa) of the resin plate.
3. The carbon fiber thermoplastic resin prepreg according to claim 1 , wherein the thermoplastic resin composition is a thermoplastic resin composition that satisfies Formula (2):
25≤(FM/FS)≤35 (2)
where,
FM represents a flexural modulus (MPa) of a resin plate formed from the thermoplastic resin composition only; and
FS represents a flexural strength (MPa) of the resin plate.
4. The carbon fiber thermoplastic resin prepreg according to claim 1 , wherein the carbon fiber bundle is a PAN-based carbon fiber bundle.
5. A carbon fiber composite material formed from the carbon fiber thermoplastic resin prepreg according to claim 1 .
6. The carbon fiber thermoplastic resin prepreg according to claim 1 , wherein a degree of circularity of a single fiber of the carbon fibers in the carbon fiber bundle is from 0.70 to 0.90,
provided that the degree of circularity is determined by Formula (4):
Degree of circularity=4 πS/L 2 (4)
where
S represents an area of a cross-section of the single fiber; and
L represents a circumferential length of the cross-section of the single fiber.
7. The carbon fiber thermoplastic resin prepreg according to claim 6 , satisfying Formula (5):
β×( Tc− 25)×(100 −Vf )>0.5 (5)
where
β represents a coefficient of linear expansion (1/° C.) of the thermoplastic resin composition;
Tc represents a lower limit temperature for molding (° C.) of the thermoplastic resin composition, when the thermoplastic resin composition has a melting point, the lower limit temperature for molding is the melting point of the composition, and when the thermoplastic resin composition does not have a melting point, the lower limit temperature for molding is a temperature at which the composition has a viscosity of 1×10 4 Pa·s; and
Vf represents a fiber volume percentage content (% by volume) of the carbon fiber thermoplastic resin prepreg.
8. The carbon fiber thermoplastic resin prepreg according to claim 6 , wherein the thermoplastic resin composition is at least one selected from the group consisting of a polypropylene resin, a polyamide resin, a modified resin of a polypropylene resin, and a modified resin of a polyamide resin.
9. A carbon fiber thermoplastic resin prepreg flake, obtained by using the carbon fiber thermoplastic resin prepreg according to claim 6 .
10. A carbon fiber-reinforced composite material, obtained by using the carbon fiber thermoplastic resin prepreg flake according to claim 9 .
11. A carbon fiber-reinforced composite material, obtained by using the carbon fiber thermoplastic resin prepreg according to claim 6 .
12. An automobile part, obtained by using the carbon fiber-reinforced composite material according to claim 11 .
13. A method for producing a carbon fiber thermoplastic resin prepreg, the method comprising: impregnating a PAN-based carbon fiber bundle having an average single fiber fineness of from 1.1 dtex to 2.4 dtex with a thermoplastic resin composition, thereby obtaining the carbon fiber thermoplastic resin prepreg,
wherein the thermoplastic resin composition is a thermoplastic resin composition that satisfies Formula (3):
20≤(FM/FS)≤40 (3)
where, FM represents a flexural modulus (MPa) of a resin plate formed from the thermoplastic resin composition only; and FS represents a flexural strength (MPa) of the resin plate, and
a single fiber of the carbon fiber in the carbon fiber bundle has plural surface asperity structures extending over 2 μm or more in the fiber longitudinal direction, and the difference of elevation between the peak and the bottom (Rp−v) in a region having a circumferential length of the single fiber of 2000 nm×a length in the fiber axial direction of 2000 nm is in the range of 60 nm to 200 nm.
14. The method according to claim 13 , wherein the thermoplastic resin composition is a film.