Positive electrode for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery
View Patent ↗An object is to provide a positive electrode for a non-aqueous electrolyte secondary battery and a non-aqueous electrolyte secondary battery that allow a high output characteristic. Included are a positive electrode collector and a positive electrode mixture layer formed on at least one surface of the positive electrode collector. The positive electrode mixture layer contains particles 3 of lithium nickel cobalt manganese oxide represented by LiNi 0.55 Co 0.2 OMn 0.25 O 2 , erbium oxyhydroxide 1 fixed on the surfaces of the particles of the lithium nickel cobalt manganese oxide 3 , tungsten trioxide 2 adhering to the surfaces of the particles of the lithium nickel cobalt manganese oxide 3 , and a binder.
1. A positive electrode for a non-aqueous electrolyte secondary battery, comprising:
a positive electrode collector; and
a positive electrode mixture layer formed on at least one surface of the positive electrode collector,
wherein the positive electrode mixture layer contains positive electrode active material particles having a layered-structure lithium transition metal oxide with rare-earth compound particles fixed on surfaces of the positive electrode active material particles, further containing tungsten-containing oxide particles and a binder,
wherein the lithium transition metal oxide forms secondary particles provided by aggregation of primary particles, and the tungsten-containing oxide is present within gaps between the primary particles,
wherein the rare-earth compound particles have an average particle size of 1 nm to 100 nm,
wherein a ratio of the rare-earth compound particles to a total molar quantity of the layered structure lithium transition metal oxide is 0.003 mol % to 0.25 mol %,
wherein a ratio of a molar quantity of the tungsten-containing oxide particles to a molar quantity of the positive electrode active material particles is 0.01 mol %-3 mol %,
wherein the tungsten-containing oxide particles are at least one of the group consisting of WO 3 , WO 2 and Li2WO 4 ,
wherein the rare-earth compound particles are at least one of the group consisting of a rare-earth hydroxide, a rare-earth oxyhydroxide and a rare-earth oxide,
wherein the lithium transition metal oxide is LiMeO 2 where Me represents at least one of the group consisting of Ni, Co and Mn.
2. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the rare-earth compound particles are a rare-earth hydroxide or a rare-earth oxyhydroxide.
3. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein a rare-earth element in the rare-earth compound particles is neodymium, samarium, or erbium.
4. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the tungsten-containing oxide particles are tungsten trioxide.
5. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium transition metal oxide is lithium cobalt oxide.
6. The positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium transition metal oxide is lithium nickel cobalt manganese oxide represented by a general formula of Li a Ni x Co y Mn z O 2 (0.95<a<1.20, 0.3≦x≦0.8, 0.1≦y≦0.4, 0.1≦z≦0.5).
7. A non-aqueous electrolyte secondary battery comprising:
the positive electrode for a non-aqueous electrolyte secondary battery according to claim 1 ;
a negative electrode containing a negative electrode active material;
a separator disposed between the positive electrode and the negative electrode; and
a non-aqueous electrolyte.