Oxynitride phosphor powder
View Patent ↗An oxynitride phosphor power has a fluorescence peak wavelength of 580 to 605 nm, the oxynitride phosphor having a higher external quantum efficiency than ever before. The oxynitride phosphor powder is an oxynitride phosphor powder containing α-SiAlON and aluminum nitride, represented by composition formula: Ca x1 Eu x2 Si 12−(y+z) Al (y+z) O z N 16−z wherein x1, x2, y and z are 0<x1≦2.50, 0.01≦x2≦0.20, 0<y≦2.3 and 1.5≦z≦3.5, or x1, x2, y and z are 0<x1≦2.70, 0.05≦x2≦0.20, 2.3≦y≦5.5 and 1≦z≦2.5.
1. An oxynitride phosphor powder containing an α-SiAlON crystal phase and an aluminum nitride crystal phase; represented by composition formula:
Ca x1 Eu x2 Si 12−(y+z) Al (y+z) O z N 16−z
wherein x1, x2, y and z are 0<x1≦2.50, 0.01≦x2≦0.20, 0<y≦2.3 and 2.5≦z≦3.5 or x1, x2, y and z are 0<x1≦2.70, 0.05≦x2≦0.20, 4.0≦y≦5.5 and 1≦z≦2.5.
2. The oxynitride phosphor powder according to claim 1 , wherein x1, x2, y and z are 0<x1≦2.50, 0.01≦x2≦0.20, 0.5<y≦2.0 and 2.5≦z≦3.2.
3. The oxynitride phosphor powder according to claim 1 , wherein the content of aluminum nitride crystal phase is from more than 0 wt % to less than 15 wt %.
4. The oxynitride phosphor powder according to claim 1 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are 7.84 Å≦a=b≦7.89 Å and 5.70 Å≦c≦5.74 Å.
5. The oxynitride phosphor powder according to claim 1 , wherein fluorescence having a peak wavelength in a wavelength region of 580 to 600 nm is emitted by excitation with light having a wavelength of 450 nm and the external quantum efficiency in the light emission is 60% or more.
6. The oxynitride phosphor powder according to claim 1 , wherein in said composition formula, 2.3<y≦2.5 and the content of aluminum nitride crystal phase is from more than 0 wt % to less than 15 wt %.
7. The oxynitride phosphor powder according to claim 1 , wherein in said composition formula, 2.5<y≦5.5 and the content of aluminum nitride crystal phase is from more than 0 wt % to less than 32 wt %.
8. The oxynitride phosphor powder according to claim 1 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are, in said composition formula, 2.3<y≦4.0, 7.90 Å≦a=b≦7.96 Å and 5.75 Å≦c≦5.79 Å.
9. The oxynitride phosphor powder according to claim 1 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are, in said composition formula, 4.0<y≦5.5, 7.95 Å≦a=b≦7.99 Å and 5.77 Å≦c≦5.80 Å.
10. The oxynitride phosphor powder according to claim 1 , wherein fluorescence having a peak wavelength in a wavelength region of 590 to 605 nm is emitted by excitation with light having a wavelength of 450 nm and external quantum efficiency in the light emission is 60% or more.
11. The oxynitride phosphor powder according to claim 1 , wherein 50% diameter (D 50 ) in a particle size distribution curve measured by a laser diffraction/scattering particle size distribution measuring apparatus is 10.0 to 20.0 μm and the specific surface area is 0.2 to 0.6 m 2 /g.
12. A method of producing an oxynitride phosphor powder comprising mixing a silicon source substance, an aluminum source substance, a calcium source substance, and a europium source substance to give a composition represented by composition formula:
Ca x1 Eu x2 Si 12−(y+z) Al (y+z) O z N 16−z
wherein x1, x2, y and z are 0<x1≦2.50, 0.01≦x2≦0.20, 0<y≦2.3 and 2.5≦z≦3.5, or x1, x2, y and z are 0<x1≦2.70, 0.05≦x2≦0.20, 4.0≦y≦5.5 and 1≦z≦2.5, and firing the mixture to produce an oxynitride phosphor powder containing an α-SiAlON crystal phase and an aluminum nitride crystal phase.
13. The method according to claim 12 , wherein said firing is performed at a temperature of 1,500 to 2,000° C. in an inert gas atmosphere.
14. The method according to claim 12 , wherein a fired product obtained by said firing is further heat-treated at a temperature of 1,100 to 1,600° C. in an inert gas atmosphere.
15. The method according to claim 13 , wherein a fired product obtained by said firing is further heat-treated at a temperature of 1,100 to 1,600° C. in an inert gas atmosphere.
16. The oxynitride phosphor powder according to claim 6 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are, in said composition formula, 2.3<y≦4.0, 7.90 Å≦a=b≦7.96 Å and 5.75 Å≦c≦5.79 Å.
17. The oxynitride phosphor powder according to claim 7 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are, in said composition formula, 2.3<y≦4.0, 7.90 Å≦a=b≦7.96 Å and 5.75 Å≦c≦5.79 Å.
18. The oxynitride phosphor powder according to claim 6 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are, in said composition formula, 4.0<y≦5.5, 7.95 Å≦a=b≦7.99 Å and 5.77 Å≦c≦5.80 Å.
19. The oxynitride phosphor powder according to claim 7 , wherein lattice constants of the α-SiAlON crystal phase constituting the oxynitride phosphor powder are, in said composition formula, 4.0<y≦5.5, 7.95 Å≦a=b≦7.99 Å and 5.77 Å≦c≦5.80 Å.
20. The oxynitride phosphor powder according to claim 1 , wherein said oxynitride phosphor powder emits fluorescence having a peak wavelength in a wavelength region of 580 to 605 nm by excitation with light having a wavelength of 450 nm and exhibits an external quantum efficiency in a light emission of 60% or more.
21. The oxynitride phosphor powder according to claim 1 , produced by the method of claim 12 .
22. The oxynitride phosphor powder according to claim 3 , wherein content of the aluminum nitride crystal phase is 5 wt % to less than 12 wt %.
23. The oxynitride phosphor powder according to claim 6 , wherein content of the aluminum nitride crystal phase is 1 wt % to less than 15 wt %.
24. The oxynitride phosphor powder according to claim 7 , wherein content of the aluminum nitride crystal phase is 3 wt % to less than 32 wt %.