Organic electroluminescent element

1. An organic electroluminescent device, comprising one or more light-emitting layers between an anode and a cathode opposite to each other, wherein:

at least one of the light-emitting layers contains two host materials and at least one light-emitting dopant; and

one of the two host materials comprises a host material selected from compounds each represented by any one of the following general formulae (1) to (2), and another of the two host materials comprises a host material selected from compounds each represented by the following general formula (3):

wherein a ring a represents an aromatic ring or heterocycle represented by the formula (a1) condensed at arbitrary positions of two adjacent rings, X1 represents C—R, a ring b represents a heterocycle represented by the formula (b1) condensed at arbitrary positions of two adjacent rings, Ar1 and Ar2 each represent an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, and at least one of Ar1 and Ar2 represents a substituted or unsubstituted monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, L1 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a group obtained by linking 2 to 10 of the groups, the aromatic hydrocarbon groups or aromatic heterocyclic groups in Ar1, Ar2, and L1 may each have a substituent, p represents an integer of from 0 to 7 and when p represents 2 or more, L1s may be identical to or different from each other, and R and R1 to R3 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an aralkyl group having 7 to 38 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, a dialkylamino group having 2 to 40 carbon atoms, a diarylamino group having 12 to 44 carbon atoms, a diaralkylamino group having 14 to 76 carbon atoms, an acyl group having 2 to 20 carbon atoms, an acyloxy group having 2 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkoxycarbonyl group having 2 to 20 carbon atoms, an alkoxycarbonyloxy group having 2 to 20 carbon atoms, an alkylsulfonyl group having 1 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 22 carbon atoms, or an aromatic heterocyclic group having 3 to 16 carbon atoms, and may each have a substituent;

wherein a ring c and a ring c′ each represent an aromatic ring or heterocycle represented by the formula (c1) condensed at an arbitrary position of an adjacent ring, a ring d and a ring d′ each represent a heterocycle represented by the formula (d1) condensed at an arbitrary position of an adjacent ring, and the ring c and the ring c′, or the ring d and the ring d′ may be identical to or different from each other, X2 represents C—R′ or N, Z represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a divalent linking group obtained by linking 2 to 10 of the groups, but a group linked to N comprises an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, Ar3 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, L2 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a group obtained by linking 2 to 10 of the groups, the aromatic hydrocarbon groups or aromatic heterocyclic groups in Z, Ar3, and L2 may each have a substituent, q represents an integer of from 0 to 7, and when q represents 2 or more, L2s may be identical to or different from each other, and R′ and R4 to R8 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an aralkyl group having 7 to 38 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, a dialkylamino group having 2 to 40 carbon atoms, a diarylamino group having 12 to 44 carbon atoms, a diaralkylamino group having 14 to 76 carbon atoms, an acyl group having 2 to 20 carbon atoms, an acyloxy group having 2 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkoxycarbonyl group having 2 to 20 carbon atoms, an alkoxycarbonyloxy group having 2 to 20 carbon atoms, an alkylsulfonyl group having 1 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 22 carbon atoms, or an aromatic heterocyclic group having 3 to 16 carbon atoms, and may each have a substituent;

wherein R9 to R12 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an acyl group having 2 to 20 carbon atoms, or an alkoxy group having 2 to 20 carbon atoms, 1 and m each represent an integer of 1 or 2, n represents 5 or 6, R13 and R14 each independently represent hydrogen or an alkyl group having 1 to 20 carbon atoms, and X3to X5 each independently represent C—H or N, and when n represents 2 or more, R13s, R14s, and X3s to X5s may be identical to or different from each other.

2. An organic electroluminescent device, comprising one or more light-emitting layers between an anode and a cathode opposite to each other, wherein:

at least one of the light-emitting layers contains two host materials and at least one light-emitting dopant; and one of the two host materials comprises a host material selected from compounds each represented by the following general formula (2), and another of the two host materials comprises a host material selected from compounds each represented by the following general formula (3)

wherein a ring c and a ring c′ each represent an aromatic ring or heterocycle represented by the formula (c1) condensed at an arbitrary position of an adjacent ring, a ring d and a ring d′ each represent a heterocycle represented by the formula (d1) condensed at an arbitrary position of an adjacent ring, and the ring c and the ring c′, or the ring d and the ring d′ may be identical to or different from each other, X2 represents C—R′ or N, Z represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a divalent linking group obtained by linking 2 to 10 of the groups, but a group linked to N comprises an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, Ar3 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, L2 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a group obtained by linking 2 to 10 of the groups, the aromatic hydrocarbon groups or aromatic heterocyclic groups in Z, Ar3, and L2 may each have a substituent, q represents an integer of from 0 to 7, and when q represents 2 or more, L2s may be identical to or different from each other, and R′ and R4 to R8 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an aralkyl group having 7 to 38 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, a dialkylamino group having 2 to 40 carbon atoms, a diarylamino group having 12 to 44 carbon atoms, a diaralkylamino group having 14 to 76 carbon atoms, an acyl group having 2 to 20 carbon atoms, an acyloxy group having 2 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkoxycarbonyl group having 2 to 20 carbon atoms, an alkoxycarbonyloxy group having 2 to 20 carbon atoms, an alkylsulfonyl group having 1 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 22 carbon atoms, or an aromatic heterocyclic group having 3 to 16 carbon atoms, and may each have a substituent;

wherein R9 to R12 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an acyl group having 2 to 20 carbon atoms, or an alkoxy group having 2 to 20 carbon atoms, I and m each represent an integer of 1 or 2, n represents an integer of from 1 to 6, R13 and R14 each independently represent hydrogen or an alkyl group having 1 to 20 carbon atoms, and X3to X5 each independently represent C—H or N, and when n represents 2 or more, R13s, R14s, and X3s to X5s may be identical to or different from each other, and

wherein in the general formula (3), at least two X3, X4, or X5 out of all X3s, X4s and X5s in the general formula (3) are N, and at least one carbazole group is bonded to the adjacent six-membered aromatic ring at the meta or para position.

3. An organic electroluminescent device, comprising one or more light-emitting layers between an anode and a cathode opposite to each other, wherein:

at least one of the light-emitting layers contains two host materials and at least one light-emitting dopant; and one of the two host materials comprises a host material selected from compounds each represented by the following general formula (2), and another of the two host materials comprises a host material selected from compounds each represented by the following general formula (3):

wherein a ring c and a ring c′ each represent an aromatic ring or heterocycle represented by the formula (c1) condensed at an arbitrary position of an adjacent ring, a ring d and a ring d′ each represent a heterocycle represented by the formula (d1) condensed at an arbitrary position of an adjacent ring, and the ring c and the ring c′, or the ring d and the ring d′ may be identical to or different from each other, X2 represents C—R′ or N, Z represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a divalent linking group obtained by linking 2 to 10 of the groups, but a group linked to N comprises an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, Ar3 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, L2 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a group obtained by linking 2 to 10 of the groups, the aromatic hydrocarbon groups or aromatic heterocyclic groups in Z, Ar3, and L2 may each have a substituent, q represents an integer of from 0 to 7, and when q represents 2 or more, L2s may be identical to or different from each other, and R′ and R4 to R8 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an aralkyl group having 7 to 38 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, a dialkylamino group having 2 to 40 carbon atoms, a diarylamino group having 12 to 44 carbon atoms, a diaralkylamino group having 14 to 76 carbon atoms, an acyl group having 2 to 20 carbon atoms, an acyloxy group having 2 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkoxycarbonyl group having 2 to 20 carbon atoms, an alkoxycarbonyloxy group having 2 to 20 carbon atoms, an alkylsulfonyl group having 1 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 22 carboncarbon atoms, or an aromatic heterocyclic group having 3 to 16 carbon atoms, and may each have a substituent;

wherein R9 to R12 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an acyl group having 2 to 20 carbon atoms, or an alkoxy group having 2 to 20 carbon atoms, I and m each represent an integer of 1 or 2, n represents an integer of from 1 to 6, R13 and R14 each independently represent hydrogen or an alkyl group having 1 to 20 carbon atoms, and X3to X5 each independently represent C—H or N, and when n represents 2 or more, R13s, R14s, and X3s to X5s may be identical to or different from each other, and

wherein in the general formula (3), at least one carbazole group is bonded to the adjacent six-membered aromatic ring at the meta or para position.

4. An organic electroluminescent device, comprising one or more light-emitting layers between an anode and a cathode opposite to each other, wherein:

at least one of the light-emitting layers contains two host materials and at least one light-emitting dopant; and one of the two host materials comprises a host material selected from compounds each represented by the following general formula (2), and another of the two host materials comprises a host material selected from compounds each represented by the following general formula (3):

wherein a ring c and a ring c′ each represent an aromatic ring or heterocycle represented by the formula (c1) condensed at an arbitrary position of an adjacent ring, a ring d and a ring d′ each represent a heterocycle represented by the formula (d1) condensed at an arbitrary position of an adjacent ring, and the ring c and the ring c′, or the ring d and the ring d′ may be identical to or different from each other, X2 represents C—R′ or N, Z represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a divalent linking group obtained by linking 2 to 10 of the groups, but a group linked to N comprises an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, Ar3 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms or a monocyclic aromatic heterocyclic group having 3 to 6 carbon atoms, L2 represents an aromatic hydrocarbon group having 6 to 22 carbon atoms, an aromatic heterocyclic group having 3 to 16 carbon atoms, or a group obtained by linking 2 to 10 of the groups, the aromatic hydrocarbon groups or aromatic heterocyclic groups in Z, Ar3, and L2 may each have a substituent, q represents an integer of from 0 to 7, and when q represents 2 or more, L2s may be identical to or different from each other, and R′ and R4 to R8 each independently represent hydrogen, an alkyl group having 1 to 20 carbon atoms, an aralkyl group having 7 to 38 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, an alkynyl group having 2 to 20 carbon atoms, a dialkylamino group having 2 to 40 carbon atoms, a diarylamino group having 12 to 44 carbon atoms, a diaralkylamino group having 14 to 76 carbon atoms, an acyl group having 2 to 20 carbon atoms, an acyloxy group having 2 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkoxycarbonyl group having 2 to 20 carbon atoms, an alkoxycarbonyloxy group having 2 to 20 carbon atoms, an alkylsulfonyl group having 1 to 20 carbon atoms, an aromatic hydrocarbon group having 6 to 22 carbon atoms, or an aromatic heterocyclic group having 3 to 16 carbon atoms, and may each have a substituent;

wherein R9 to R12 each independently represent hydrogen, an alkyl group having 1 to 20carbon atoms, an acyl group having 2 to 20 carbon atoms, or an alkoxy group having 2 to 20 carbon atoms, I and m each represent an integer of 1 or 2, n represents an integer of from 1 to 6, R13 and R14 each independently represent hydrogen or an alkyl group having 1 to 20 carbon atoms, and X3to X5 each independently represent C—H or N, and when n represents 2 or more, R13s, R14s, and X3s to X5s may be identical to or different from each other, and

wherein in the general formula (3), at least four X3, X4, or X5 out of all X3s, X4s and X5s in the general formula (3) are N.