IP Library Granted Patent US 9,650,504
Granted Patent B2
US 9,650,504 · App. 14/389,543 · Granted May 16, 2017

High-flow fiber reinforced polypropylene composition

Inventors: Erwin Kastner (Linz, AT); Jochen Kastl (Ottensheim, AT); Markus Hemmeter (Linz, AT)
Assignee: Borealis AG
C08L23/10C08J9/0061C08L23/0815C08L23/16C08L2205/02C08L2205/025
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Quick Facts
Patent No.
US 9,650,504
App. No.
14/389,543
Granted
May 16, 2017
Kind
B2
Abstract

Fiber reinforced composition comprising a heterophasic propylene copolymer, a propylene homopolymer and/or a propylene copolymer, and fibers having an average diameter of 12.0 μm or less, wherein the propylene copolymer comprises not more than 2.0 wt.-% C2 to C10 α-olefins other than propylene, the propylene homopolymer and the propylene copolymer have a melt flow rate MFR 2 (230° C.) of at least 100 g/10 min, and the composition has a melt flow rate MFR 2 (230° C.) of at least 10 g/10 min.

Claims (32)

1. A fiber reinforced composition comprising,

(a) a heterophasic propylene copolymer (HECO),

(b) a propylene homopolymer (H-PP1) and/or a propylene copolymer (C-PP1), and

(c) fibers (F) having an average diameter of 12.0 μm or less and an aspect ratio of 150 to 450,

wherein

(i) the propylene copolymer (C-PP1) comprises not more than 2.0 wt.-% C 2 to C 10 α-olefins other than propylene,

(ii) the propylene homopolymer (H-PP1) and the propylene copolymer (C-PP1) have a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 of at least 50 g/10min, and

(iii) the fiber reinforced composition has a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 of at least 10 g/10 min.

2. The fiber reinforced composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises a polypropylene matrix (M-PP) and dispersed therein an elastomeric copolymer (E1) comprising units derived from

propylene and

ethylene and/or C4 to C20 α-olefin.

3. The fiber reinforced composition according to claim 2 , wherein the polypropylene matrix (M-PP) has a lower melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 than the propylene homopolymer (H-PP1) or the propylene copolymer (C-PP1).

4. The fiber reinforced composition according to claim 1 , wherein the composition comprises

(a) 10.0 to 50.0 wt.-% of the heterophasic propylene copolymer (HECO),

(b) 20.0 to 70.0 wt.-% of the propylene homopolymer (H-PP1), of the propylene copolymer (C-PP1), or of the mixture of the propylene homopolymer (H-PP1) and the propylene copolymer (C-PP1), and

(c) 5.0 to 50.0 wt.-% of fibers (F), based on the total weight of the fiber reinforced composition.

5. The fiber reinforced composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has

(a) a xylene cold soluble content (XCS) measured according ISO 6427 (23 ° C.) of not more than 35 wt.-%, and/or

(b) a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 of more than 15 g/10 min, and/or

(c) a total C 2 to C 10 α-olefin content other than propylene of 10 to 30 wt.-%.

6. The fiber reinforced composition according to claim 1 , wherein the propylene homopolymer (H-PP1) has a melt flow rate MFR 2 (230 ° C.) measured according to ISO 1133 in the range of 50 to 150 g/10 min.

7. The fiber reinforced composition according to claim 1 , wherein the fibers (F) are selected from the group consisting of glass fibers, metal fibers, ceramic fibers and graphite fibers.

8. An automotive article comprising the fiber reinforced composition according to claim 1 .

9. A foamed article, comprising the fiber reinforced composition according to claim 1 .

10. A process for the preparation of the fiber reinforced composition according to claim 1 comprising, the steps of adding

(a) the heterophasic propylene copolymer (HECO),

(b) the propylene homopolymer (H-PP1), the propylene copolymer (C-PP1), or the mixture of the propylene homopolymer (H-PP1) and the propylene copolymer (C-PP1), and

(c) the fibers (F)

to an extruder and extruding the same obtaining said fiber reinforced composition.

11. The fiber reinforced composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises a polypropylene matrix (M-PP) that is a propylene homopolymer (H-PP2) and dispersed therein an elastomeric copolymer (E1) comprising units derived from

propylene and

ethylene and/or C4 to C20 α-olefin.

Assignments (2)
CHANGE OF ADDRESS Recorded Feb 23, 2022
From: BOREALIS AG
To: BOREALIS AG
Reel/Frame 059219/0949 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 6, 2015
From: KASTNER, ERWIN; KASTL, JOCHEN; HEMMETER, MARKUS
To: BOREALIS AG
Reel/Frame 034642/0147 →
Priority Claims (1)
EP 12163221 · Apr 4, 2012 · regional
Continuity (1)
Related Publication 20150368449A1 · Dec 24, 2015