Silicate-coated MFI-type zeolite, method of producing the same, and method of producing p-xylene using the same
A silicate-coated MFI-type zeolite is obtained by coating an MFI-type zeolite with a silicate, and a peak area ratio b/a of a peak b at 2θ=8.4 to 9.7° to a peak a at 2θ=7.0 to 8.4° in an X-ray diffraction spectrum is 1 or more, and a pKa value measured by a Hammett indicator is +3.3 or more.
1. A method of producing a silicate-coated MFI-type zeolite comprising:
synthesizing hydrothermally using a silica source, an aluminum source, a structure directing agent, and a fluorine source to obtain an MFI-type zeolite having a peak area ratio b′/a′ of a peak b′ at 2θ=8.4 to 9.7° to a peak a′ at 2θ=7.0 to 8.4° in an X-ray diffraction spectrum of 1 or more; and
coating the MFI-type zeolite with a silicate by synthesizing hydrothermally using a silica source and a structure directing agent and without using a fluorine source to obtain the silicate-coated MFI-type zeolite, wherein a peak area ratio b/a of a peak b at 2θ=8.4 to 9.7° to a peak a at 2θ=7.0 to 8.4° in an X-ray diffraction spectrum of the silicate-coated MFI-type zeolite is 1 or more and a pKa value measured by a Hammett indicator is +3.3 or more.
2. The method of producing the silicate-coated MFI-type zeolite according to claim 1 , further comprising removing aluminum in sites other than a skeleton of the MFI-type zeolite.
3. The method of producing the silicate-coated MFI-type zeolite according to claim 1 , further comprising:
before the coating the MFI-type zeolite with the silicate, subjecting the MFI-type zeolite to an ion-exchange treatment to obtain the MFI-type zeolite having an amount of aluminum in sites other than a skeleton of the MFI-type zeolite of 10% or less.