Copolymer, rubber composition using same, and tire
The present invention relates to a copolymer including a monomer unit (a) derived from a conjugated diene having not more than 12 carbon atoms and a monomer unit (b) derived from farnesene; a process for producing the copolymer including at least the step of copolymerizing a conjugated diene having not more than 12 carbon atoms with farnesene; a rubber composition including (A) the copolymer, (B) a rubber component and (C) carbon black; a rubber composition including (A) the copolymer, (B) a rubber component and (D) silica; a rubber composition including (A) the copolymer, (B) a rubber component, (C) carbon black and (D) silica; and a tire using the rubber composition at least as a part thereof.
1. A rubber composition comprising:
(A) a copolymer comprising a monomer unit (a) derived from a conjugated diene having not more than 12 carbon atoms and a monomer unit (b) derived from farnesene;
(B) a rubber component; and
(C) carbon black,
wherein a content of the copolymer (A) and the carbon black (C) in the rubber composition is from 0.1 to 100 parts by mass and from 0.1 to 150 parts by mass, respectively, on the basis of 100 parts by mass of the rubber component (B).
2. The rubber composition according to claim 1 , wherein the carbon black (C) has an average particle size of from 5 to 100 nm.
3. The rubber composition according to claim 1 , further comprising silica (D) having an average particle size of from 0.5 to 200 nm.
4. The rubber composition according to claim 3 , wherein a content of the copolymer (A) and the silica (D) in the rubber composition is from 0.1 to 100 parts by mass and from 0.1 to 150 parts by mass, respectively, on the basis of 100 parts by mass of the rubber component (B).
5. The rubber composition according to claim 3 , wherein a content of the copolymer (A), the carbon black (C) and the silica (D) in the rubber composition is from 0.1 to 100 parts by mass, from 0.1 to 150 parts by mass and from 0.1 to 150 parts by mass, respectively, on the basis of 100 parts by mass of the rubber component (B).
6. The rubber composition according to claim wherein the rubber component (B) is at least one rubber selected from the group consisting of a styrene-butadiene rubber, a natural rubber, a butadiene rubber and an isoprene rubber.
7. A tire comprising the rubber composition according to claim 1 as a part thereof.
8. The rubber composition according to claim 1 , wherein the monomer unit (b) is a monomer unit derived from β-farnesene.
9. The rubber composition according to claim 1 , wherein a mass ratio of the monomer unit (a) to a sum of the monomer unit (a) and the monomer unit (b) in the copolymer is from 1 to 99% by mass.
10. The rubber composition according to claim 1 , wherein the copolymer has a molecular weight distribution (Mw/Mn) of from 1.0 to 4.0.
11. The rubber composition according to claim 1 , wherein the conjugated diene having not more than 12 carbon atoms is at least one compound selected from the group consisting of butadiene and myrcene.
12. The rubber composition according to claim 1 , wherein the conjugated diene having not more than 12 carbon atoms is butadiene.
13. The rubber composition according to claim wherein the copolymer has a weight average molecular weight (Mw) of from 2,000 to 500,000.
14. The rubber composition according to claim 1 , wherein the copolymer has a melt viscosity of from 0.1 to 3,000 Pass as measured at 38° C.
15. The rubber composition according to claim 1 , wherein the copolymer is produced by conducting an anionic polymerization in the presence of an organic metal initiator.
16. The rubber composition according to claim 1 , further comprising silica (D).
17. The rubber composition according to claim 1 , wherein a content of the copolymer (A) and the carbon black (C) in the rubber composition is from 0.1 to 100 parts by mass and from 20 to 150 parts by mass, respectively, on the basis of 100 parts by mass of the rubber component (B).