Hot-dip galvannealed hot-rolled steel sheet and process for producing same
View Patent ↗In a high strength hot-dip galvannealed hot-rolled steel sheet that has an excellent hole expansibility suitable for a stretch flanging and preferably has a high yield ratio and a tensile strength of at least 650 MPa, a hot-rolled steel sheet used as a base material for plating has a chemical composition comprising: in mass %, C: from at least 0.01 and at most 0.20%; Si: at most 0.50%; Mn: from at least 0.01% to at most 1.30%; P: at most 0.05%; S: at most 0.01%; N: at most 0.01%; Al: at most 0.50%; and Ti: from at least 0.05% to at most 0.50%, and a steel structure consisting of a polygonal ferrite having at least 80 area % and the remainder containing one kind or two or more kinds selected from bainitic ferrite, bainite, pearlite, and cementite.
1. A hot-dip galvannealed hot-rolled steel sheet having a hot-dip galvannealed layer on a surface of a hot-rolled steel sheet, characterized by having a chemical composition consisting of, in mass %, C: at least 0.01and at most 0.20%; Si: at most 0.50%; Mn: at least 0.01% and at most 0.49%; P: at most 0.05%; S: at most 0.01%; N: at most 0.01%; Al: at most 0.50%; Ti: at least 0.14% and at most 0.50%; and at least one element selected from Ni: 0.001 to 0.50%, Cu: 0.001 to 0.50%, V:0.001 to 0.50% and Bi:0.001 to 0.01%, a remainder of Fe and impurities, and optionally one element or two or more elements in mass % selected from Cr: at most 0.80%; Nb: at most 0.1%; Ca: at most 0.01%, and
by having a steel structure containing a polygonal ferrite having at least 93 area % and the remainder consisting of one kind or two or more kinds selected from bainitic ferrite, bainite, pearlite, and cementite,
wherein the hot-dip galvannealed hot-rolled steel sheet has a mechanical property of at least 650 MPa of a tensile strength by forming non-coherent Ti carbide in the steel and precipitation-strengthening ferrite, and the hot-dip galvannealed hot-rolled steel sheet has a mechanical property in which a product of a limiting hole expansion ratio and a tensile strength is at least 60000 MPa-% the limiting hole expansion ratio being obtained by a hole expanding test specified by the Japan Iron and Steel Federation Standards JFS T 1001.
2. The hot-dip galvannealed hot-rolled steel sheet as set forth in claim 1 , wherein the hot-dip galvannealed hot-rolled steel sheet has a yield ratio of at least 80%, the yield ratio being a ratio of 0.2 proof stress to the tensile strength.
3. A process for producing a hot-dip galvannealed hot-rolled steel sheet having a steel structure containing a polygonal ferrite having at least 93 area % and the remainder consisting of one kind or two or more kinds selected from bainitic ferrite, bainite, pearlite, and cementite, the process comprising the following steps (A) to (C):
(A) a hot rolling step comprising the steps of: after reheating a slab having a chemical composition consisting of, in mass %, C: at least 0.01 and at most 0.20%; Si at most 0.50%; Mn: at least 0.01% and at most 0.49%; P: at most 0.05%; S: at most 0.01%; N: at most 0.01%; Al: at most 0.50%; and Ti: at least 0.14% and at most 0.50%, a remainder of Fe and impurities and optionally one element or two or more elements in mass% selected from in mass%, Cr: at most 0.80%; Ni: at most 0.50%; Cu: at most 0.50%; one or two elements in mass% selected from V: at most 0.5%; and Nb: at most 0.1% and one element or two or more elements in mass % selected from Ca: at most 0.01%. and Bi: at most 0.01% to a temperature of at least 1100° C. and at most 1350° C.; subjecting the slab to hot rolling; completing the hot rolling within a temperature range of at least 850° C. and at most 980° C. to thereby produce a hot-rolled steel sheet; subjecting the hot-rolled steel sheet to a primary cooling treatment, a holding treatment, and a secondary cooling treatment in sequence, the primary cooling treatment cooling the hot-rolled steel sheet to a temperature range of at least 720° C. and at most 800° C. by a water cooling unit, the holding treatment holding the hot-rolled steel sheet for a period of at least Δt seconds defined by the following formula in a temperature range of at least 650° C. and at most 800° C., the secondary cooling treatment cooling the hot-rolled steel sheet to a temperature range of at least 400° C. and at most 650° C.; and coiling the hot-rolled steel sheet in a temperature range of at least 400° C. and at most 650° C.,
Δ t (second)=5·Mn 4 (1)
where Mn in the formula (1) means a Mn content (unit: mass %) in steel,
(B) a pickling step for subjecting the hot-rolled steel sheet produced by the hot rolling step to a pickling treatment; and
(C) a continuous hot-dip galvanizing step comprising the steps of: heating the hot-rolled steel sheet produced by the pickling step to a temperature range of at least 650° C. and at most 800° C.; cooling and subjecting the hot-rolled steel sheet to a hot-dip galvanizing treatment; and holding the hot-rolled steel sheet in a temperature range of at least 460° C. and at most 600° C. to thereby subject the hot-rolled steel sheet to an alloying treatment.