Fluoropolymer compositions
View Patent ↗The present invention relates to a composition for solubilizing a fluoropolymer, comprising a solvent blend of a) compound of formula (I) R 1 —C(═O)—NR 2 R 3 wherein R 1 and R 2 and R 3 are defined as in the specification and b) dimethylsulfoxide (DMSO). The invention also relates to the process for the preparation of the composition and its uses. The invention is also the use of the fluoropolymer composition for coating applications.
1. A composition, notably for solubilizing a fluoropolymer comprising:
a solvent blend comprising:
a) at least one Compound of formula (I):
R 1 C(═O)NR 2 R 3 (I)
wherein:
R 1 is an aliphatic saturated group, that can be linear or branched, having 1 to 6 carbon atoms, and substituted by one or more functional groups selected from a group consisting of —C(═O)OR and —C(═O)NR 4 R 5 , R being an alkyl group having 1 to 6 carbon atoms, and R 4 and R 5 , identical or different, being methyl or ethyl groups;
R 2 and R 3 , identical or different, being methyl or ethyl groups;
b) dimethylsulfoxide (DMSO).
2. The composition according to claim 1 , the compound of formula (I) is MeO(O═)C—Z—C(═O)NR 2 R 3 , wherein Z is a linear or branched divalent alkylene group comprising 2 to 5 carbon atoms and R 2 and R 3 are previously defined.
3. The composition according to claim 1 , the compound of formula (I) is a blend comprising:
a compound of formula (I) wherein R 1 is —CH(CH 2 —CH 3 )—CH 2 —C(═O)OMe,
a compound of formula (I) wherein R 1 is —CH 2 —CH(CH 2 —CH 3 )—C(═O)OMe,
a compound of formula (I) wherein R 1 is —CH(CH 3 )—CH 2 —CH 2 —C(═O)OMe, and
a compound of formula (I) wherein R 1 is —CH 2 —CH 2 —CH(CH 3 )—C(═O)OMe.
4. The composition according to claim 3 , wherein said blend further comprises a compound of formula (I) wherein R 1 is —(CH 2 ) 4 —C(═O)OMe.
5. The composition according to claim 1 , wherein said compound of formula (I) is R 4 R 5 NC(═O)—Z—C(O)NR 2 R 3 , wherein Z is a linear or branched divalent alkylene group comprising 2 to 5 carbon atoms and R 2 , R 3 , R 4 and R 5 are previously defined.
6. The composition according to claim 1 , wherein said compound of formula (I) is a blend of:
RO(O═)C—Z—C(═O)NR 2 R 3 ; and
R 4 R 5 NC(═O)—Z—C(═O)NR 2 R 3 ,
wherein Z is a linear or branched divalent alkylene group comprising 2 to 5 carbon atoms and R, R 2 , R 3 , R 4 , and R 5 are previously defined.
7. The composition according to claim 1 , wherein the weight ratio between the compound of formula (I) and DMSO is of from 1/99 to 99/1.
8. The composition according to claim 1 , further comprising a fluoropolymer solubilized in the solvent blend.
9. The composition according to claim 1 , wherein the fluoropolymer is polyvinylidene fluoride (PDVF) and copolymer of vinylidene fluoride with comonomers hexafluoropropylene (HFP) and/or chlorotrifluoroethylene (CTFE).
10. The composition according to claim 9 , wherein the amount of fluoropolymer is of from 0.1 to 15% by weight.
11. The composition according to claim 1 , wherein R 1 is a group of formula —Z—C(═O)OR′, with Z a linear or branched divalent alkylene group comprising 2 to 5 carbon atoms and R′ is an alkyl group comprising 1 to 4 carbon atoms.