Rubber composition for tire, and pneumatic tire
View Patent ↗A rubber composition for tires comprises: per 100 parts by weight of diene rubber containing from 5 to 50 wt. % of modified BR having a vinyl unit content of 10 to 60 wt. %, from 2 to 50 parts by weight of an aromatic modified terpene resin having a softening point of 100 to 130° C., and a total content of 60 to 130 parts by weight of two types of silica, that is silica X and silica Y; a proportion of the silica relative to a total amount of a reinforcing filler containing carbon black being 85 wt. % or greater; a nitrogen adsorption specific surface area of the silica X is 140 m 2 /g or greater; and a nitrogen adsorption specific surface area of the silica Y is greater than 100 m 2 /g and less than 140 m 2 /g.
1. A rubber composition for tires comprising: per 100 parts by weight of diene rubber containing from 5 to 50 wt. % of terminal-modified butadiene rubber (modified BR) having a vinyl unit content of 10 to 60 wt. %,
from 2 to 50 parts by weight of an aromatic modified terpene resin having a softening point of 100 to 130° C., and
a total content of 60 to 130 parts by weight of two types of silica, that is silica X and silica Y;
a proportion of the silica relative to a total amount of a reinforcing filler containing the silica X, the silica Y, and an optionally compounded carbon black being 85 wt. % or greater;
a nitrogen adsorption specific surface area of the silica X being 140 m 2 /g or greater and less than 185 m 2 /g;
a nitrogen adsorption specific surface area of the silica Y being greater than 100 m 2 /g and less than 140 m 2 /g;
a relationship x/7<y x/6 being satisfied where a compounded amount of the silica X relative to 100 parts by weight of the diene rubber is x parts by weight and a compounded amount of the silica Y relative to 100 parts by weight of the diene rubber is y parts by weight; and
a functional group of the modified butadiene rubber being at least one type selected from a group consisting of a polyorganosiloxane group, a hydroxyl group-containing polyorganosiloxane structure, an alkoxysilyl group, a hydroxyl group, an aldehyde group, a carboxyl group, an amino group, an imino group, an epoxy group, an amide group, a thiol group, and an ether group.
2. The rubber composition for tires according to claim 1 , wherein the functional group of the terminal-modified butadiene rubber is a polyorganosiloxane group.
3. The rubber composition for tires according to claim 1 , wherein the diene rubber further contains from 25 to 95 wt. % of terminal-modified styrene butadiene rubber.
4. A pneumatic tire using the rubber composition for tires described in claim 1 .
5. The rubber composition of claim 1 , wherein the diene rubber further comprises from 25 to 95 wt % of a second diene rubber including natural rubber except the terminal-modified butadiene rubber.