IP Library Granted Patent US 10,837,127
Granted Patent B2
US 10,837,127 · App. 14/395,250 · Granted Nov 17, 2020

Carbon fiber bundle and method of producing carbon fiber bundle

Inventors: Takayuki Kiriyama (Toyohashi, JP); Naoki Sugiura (Toyohashi, JP); Masahiro Hata (Toyohashi, JP)
Assignee: Mitsubishi Chemical Corporation
D01F9/22C08K7/06D01F6/18D01F6/38D01F9/225D10B2101/12Y10T428/2918
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Quick Facts
Patent No.
US 10,837,127
App. No.
14/395,250
Granted
Nov 17, 2020
Kind
B2
Abstract

Provided are carbon fiber bundles which have high knot strength even if the single fiber fineness is large, and which have excellent handling properties and processability. The carbon fiber bundles have a single fiber fineness of 0.8-2.5 dtex, knot strength of 298 N/mm 2 or greater. This method of producing carbon fibers having knot strength of 298 N/mm 2 or greater involves a heat treatment step for heat treating, for 50-150 minutes, specific polyacrylonitrile-based precursor fiber bundles described in the description in an oxidizing atmosphere rising in temperature in the temperature range of 220-300° C.

Claims (6)

1. A carbon fiber bundle having a single fiber fineness of at least 0.8 dtex to no more than 2.5 dtex, and a knot strength of at least 298 N/mm 2 ,

wherein the carbon fiber bundle is prepared by a heat treatment of a polyacrylonitrile-based precursor fiber bundle having a single fiber fineness of at least 1.7 dtex to no more than 5.0 dtex,

wherein the polyacrylonitrile-based precursor fiber bundle consists of a polyacrylonitrile-based copolymer and a copolymer comprising 1 to 4.0 mole % of hydroxyalkyl methacrylate units.

2. The carbon fiber bundle according to claim 1 , wherein the polyacrylonitrile-based precursor fiber bundle consists of a polyacrylonitrile-based copolymer and a copolymer comprising 1.2 to 4.0 mole % of hydroxyalkyl methacrylate units.

3. The carbon fiber bundle according to claim 1 , wherein the polyacrylonitrile-based precursor fiber bundle consists of a polyacrylonitrile-based copolymer and a copolymer comprising 1.5 to 4.0 mole % of hydroxyalkyl methacrylate units.

4. The carbon fiber bundle according to claim 1 , wherein the polyacrylonitrile-based precursor fiber bundle consists of a polyacrylonitrile-based copolymer and a copolymer comprising 1.5 to 3.0 mole % of hydroxyalkyl methacrylate units.

Assignments (2)
MERGER Recorded Jun 28, 2017
From: MITSUBISHI RAYON CO., LTD.
To: MITSUBISHI CHEMICAL CORPORATION
Reel/Frame 043027/0929 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 17, 2014
From: KIRIYAMA, TAKAYUKI; SUGIURA, NAOKI; HATA, MASAHIRO
To: MITSUBISHI RAYON CO., LTD.
Reel/Frame 033972/0488 →
Priority Claims (1)
JP 2012-094550 · Apr 18, 2012 · national
Continuity (1)
Related Publication 20150114262A1 · Apr 30, 2015