TiO 2 based scrubbing granules, and methods of making and using such TiO 2 based scrubbing granules are described. TiO2-based scrubbing granules include granulated TiO 2 and about 0.5% to about 20% dry weight inorganic salt binder. Other TiO 2 based scrubbing granules include unsintered granulated TiO2 and about 0.5% to about 20% dry weight inorganic salt binder. Inorganic salt binder include sodium aluminate. Methods of making TiO 2 based scrubbing granules include i) combining TiO 2 particles with inorganic salt binder to form TiO 2 -binder mixture comprising from about 0.5% to about 20% dry weight binder; ii) granulating the TiO2-binder mixture; and drying the granulated TiO 2 -binder mixture to form TiO2-based scrubbing granules. Methods of using such TiO 2 -based scrubbing granules include introducing TiO 2 -based scrubbing granules to remove adherent deposits on an inner surface of a reactor or heat exchanger during processes of forming TiO 2 particles and finishing the formed TiO 2 particles into finished pigment products.
1. A method of making TiO 2 -based scrubbing granules comprising:
i. combining TiO 2 particles with sodium aluminate binder to form TiO 2 -binder mixture comprising from about 0.5% to about 20% dry weight binder;
ii. granulating the TiO 2 -binder mixture; and
iii. drying the granulated TiO 2 -binder mixture to form TiO 2 -based scrubbing granules;
further comprising compacting the TiO 2 -binder mixture under pressure to form the TiO 2 -binder mixture into compacted briquettes; and
comprising breaking the compacted briquettes into TiO 2 -binder granules having average size in a range of from about 1 mm to about 25 mm.
2. The method of claim 1 , wherein the binder further comprises an inorganic metal salt.
3. The method of claim 1 , wherein the binder further comprises an inorganic metal salt selected from the group consisting of sodium sulfate, sodium phosphate, sodium silicate, sodium chloride, sodium hexametaphosphate, aluminum sulfate, and combinations thereof.
4. The method of claim 1 , further comprising breaking the compacted briquettes into TiO 2 -binder granules having an average size in a range of from about 1 mm to about 25 mm.
5. The method of claim 1 , wherein drying the TiO 2 -binder mixture comprises heating at a temperature in a range of from about 100° C. to about 700° C.
6. The method of claim 1 , wherein the TiO 2 particles are produced by a chloride or sulfate TiO 2 manufacturing process.
7. The method of claim 1 , wherein the TiO 2 -based scrubbing granules are unsintered.