Processes for preparing lithium hydroxide
There are provided methods for preparing lithium hydroxide. For example, such methods can comprise submitting an aqueous composition comprising a lithium compound to an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide.
1. A process for preparing lithium hydroxide, said process comprising:
leaching an acid roasted lithium-containing material with water so as to obtain an aqueous composition comprising Li + and at least one metal ion;
reacting said aqueous composition comprising Li + and said at least one metal ion with a base so as to obtain a pH of about 4.5 to about 6.5 and thereby at least partially precipitating said at least one metal ion under the form of at least one hydroxide so as to obtain a precipitate comprising said at least one hydroxide and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
optionally reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with another base so as to obtain a pH of about 9.5 to about 11.5, and with optionally at least one metal carbonate, thereby at least partially precipitating at least one metal ion optionally under the form of at least one carbonate so as to obtain a precipitate optionally comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
contacting said aqueous composition comprising Li + and having a reduced content of said at least one metal ion with an ion exchange resin so as to at least partially remove at least one metal ion from said composition, thereby obtaining an aqueous composition comprising lithium sulphate; and
submitting said aqueous composition comprising said lithium sulphate to an electrolysis under conditions suitable for converting at least a portion of said lithium sulphate into lithium hydroxide, wherein during said electrolysis, said aqueous composition comprising lithium sulphate has a pH of greater than 7.
2. The process of claim 1 , wherein said process is carried out in an electrolysis cell comprising membranes and said lithium sulphate has a pH greater than 8.0.
3. The process of claim 2 , wherein during said process, temperature of said aqueous composition comprising lithium sulphate is at least substantially maintained at a value of about 40 to about 60 ° C.
4. The process of claim 3 , wherein during said process electrical current is at least substantially maintained at a density of about 400 to about 600 A/m 2 .
5. The process of claim 3 , wherein during said process voltage is at least substantially maintained at a constant value that is about 3 to about 10 V.
6. The process of claim 3 , wherein during said electrolysis, said aqueous composition comprising lithium sulphate has a pH between greater than 7 and 14.
7. The process of claim 1 , wherein said lithium sulphate has a pH greater than 8.5.
8. The process of claim 1 , wherein during said process, temperature of said aqueous composition comprising lithium sulphate is at least substantially maintained at a value of about 20 to about 80° C.
9. The process of claim 1 , wherein during said process said aqueous composition comprising lithium sulphate is at least substantially maintained at a concentration of lithium sulphate of about 10 to about 20 g/L.
10. The process of claim 1 , comprising reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with another base so as to obtain a pH of about 9.5 to about 11.5, and with at least one metal carbonate, thereby at least partially precipitating at least one metal ion under the form of at least one carbonate so as to obtain a precipitate comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate.
11. A process for preparing lithium hydroxide, said process comprising:
leaching an acid roasted lithium-containing material with water so as to obtain an aqueous composition comprising Li + and at least one metal ion;
reacting said aqueous composition comprising Li + and said at least one metal ion with a base so as to obtain a pH of about 4.5 to about 6.5 and thereby at least partially precipitating said at least one metal ion under the form of at least one hydroxide so as to obtain a precipitate comprising said at least one hydroxide and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
optionally reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with another base so as to obtain a pH of about 9.5 to about 11.5, and with optionally at least one metal carbonate, thereby at least partially precipitating at least one metal ion optionally under the form of at least one carbonate so as to obtain a precipitate optionally comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
contacting said aqueous composition comprising Li + and having a reduced content of said at least one metal ion with an ion exchange resin so as to at least partially remove at least one metal ion from said composition, thereby obtaining an aqueous composition comprising a lithium compound; and
submitting said aqueous composition comprising said lithium compound to an electrolysis or an electrodialysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide.
12. The process of claim 11 , wherein said aqueous composition is submitted to an electrolysis and during said electrolysis, said aqueous composition comprising said lithium compound is at least substantially maintained at a pH having a value of about 9.5 to about 12.5.
13. The process of claim 11 , wherein said aqueous composition is submitted to an electrolysis, said aqueous composition comprising said lithium compound has a pH between 7 and 14.5.
14. The process of claim 13 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.0 to about 6.2.
15. The process of claim 14 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 9.5 to about 11.5.
16. The process of claim 15 , wherein said acid roasted lithium-containing material is β-spodumene that has been previously reacted with H 2 SO 4 .
17. The process of claim 11 , wherein during said electrodialysis, said pH is at least substantially maintained at a value of about 11 to about 12.
18. The process of claim 11 , wherein during said process electrical current is at least substantially maintained at a constant value.
19. The process of claim 18 , wherein during said process voltage is at least substantially maintained at a constant value.
20. The process of claim 11 , comprising reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with another base so as to obtain a pH of about 9.5 to about 11.5, and with at least one metal carbonate, thereby at least partially precipitating at least one metal ion under the form of at least one carbonate so as to obtain a precipitate comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate.