ADHESIVE AGENT COMPOSITION HAVING IMPROVED BUBBLE STABILITY AND METHOD FOR PREPARING SAME
Provided is an adhesive composition, comprising: a copolymer in which a monomer containing 5 to 50 parts by weight of a polar functional group with respect to 100 parts by weight of a (meta) acrylic acid ester-based monomer is polymerized; and a hollow glass filler or bubbles. Also provided is a method for preparing the adhesive composition, comprising the steps of: preparing the copolymer by polymerizing 5 to 50 parts by weight of the monomer containing the polar function group, with respect to 100 parts by weight of the (meta) acrylic acid ester-based monomer; preparing a mixture by adding a surfactant, a photoinitiator, and a photocuring agent to the copolymer; and adding to the mixture the hollow glass filler or the bubbles.
1 . An adhesive composition comprising:
a copolymer in which 5 parts by weight to 50 parts by weight of a polar functional group-containing monomer is polymerized based on 100 parts by weight of a (meth)acrylic acid ester monomer, and
hollow glass fillers or bubbles.
2 . The adhesive composition according to claim 1 , wherein the acrylic acid ester monomer comprises at least one selected from the group consisting of methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, t-butyl (meth)acrylate, sec-butyl (meth)acrylate, pentyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, 2-ethylbutyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, isononyl (meth)acrylate, lauryl (meth)acrylate, tetradecyl (meth)acrylate, and combinations thereof.
3 . The adhesive composition according to claim 1 , wherein the polar functional group-containing monomer comprises at least one selected from the group consisting of hydroxyl group-containing monomers, carboxyl group-containing monomers, nitrogen-containing monomers, and combinations thereof.
4 . The adhesive composition according to claim 1 , wherein the hollow glass fillers or the bubbles have a spherical shape.
5 . The adhesive composition according to claim 1 , wherein the hollow glass fillers or the bubbles have a diameter from 20 μm to 300 μm.
6 . The adhesive composition according to claim 1 , wherein the hollow glass fillers are present in an amount of 0.1 parts by weight to 20 parts by weight based on 100 parts by weight of the (meth)acrylic acid ester monomer.
7 . The adhesive composition according to claim 1 , wherein the bubbles are present in an amount of 0.1 vol % to 10 vol % per unit volume.
8 . The adhesive composition according to claim 1 , wherein the adhesive composition has a density from 0.4 g/m 3 to 0.8 g/m 3 .
9 . A method for preparing an adhesive composition, comprising:
preparing a copolymer by polymerizing 5 parts by weight to 50 parts by weight of a polar functional group-containing monomer based on 100 parts by weight of a (meth)acrylic acid ester monomer;
preparing a mixture by adding a surfactant, a photoinitiator and a photocuring agent to the copolymer; and
adding hollow glass fillers to the mixture or injecting bubbles into the mixture.
10 . The method according to claim 9 , further comprising:
curing the mixture comprising the hollow glass filler or the bubbles therein.