Method for manufacturing a thin-film semiconductor device using an etching solution for an aluminum oxide film
View Patent ↗An etching solution includes: phosphoric acid having concentration of 30% by weight to 80% by weight; nitric acid having concentration of 10% by weight or less; and surfactant having concentration of 0.0005% by weight to 0.0050% by weight, wherein the etching solution is used for etching an aluminum oxide film having film density of 2.80 g/cm 3 to 3.25 g/cm 3 .
1. A manufacturing method of a thin-film semiconductor device, the manufacturing method comprising:
forming an aluminum oxide film having film density of 2.80 g/cm 3 to 3.25 g/cm 3 above an oxide semiconductor layer;
providing a through-hole in the aluminum oxide film by etching the aluminum oxide film with use of an etching solution, the etching solution including phosphoric acid having concentration of 30% by weight to 80% by weight, nitric acid having concentration of 10% by weight or less, and surfactant having concentration of 0.0005% by weight to 0.0050% by weight; and
embedding, in the through-hole provided in the aluminum oxide film, an electrode to be electrically connected with the oxide semiconductor layer.
2. The manufacturing method of claim 1 , wherein
the phosphoric acid has concentration of 50% by weight to 70% by weight, and
the nitric acid has concentration of 2% by weight to 4% by weight.
3. The manufacturing method of claim 1 , further comprising, between forming the aluminum oxide film and providing the through-hole in the aluminum oxide film:
forming a protection film on the aluminum oxide film;
providing a through-hole in the protection film by etching the protection film with use of fluorine-based gas; and
performing plasma processing, with use of oxygen-based gas and without fluorine-based gas, on part of the aluminum oxide film that is exposed through the through-hole provided in the protection film.
4. The manufacturing method of claim 3 , wherein
the protection film has a single-layer structure consisting of any one of a silicon nitride film, a silicon oxide film, and a silicon oxynitride film, or a multi-layer structure consisting of at least two of the silicon nitride film, the silicon oxide film, and the silicon oxynitride film.