ADHESIVE COMPOSITION HAVING HIGH FLEXIBILITY
The present invention relates to an adhesive composition comprising: an alkyl acrylic acid ester monomer having an alkyl carbon number of 2 to 14; an acrylic acid ester monomer containing a hydroxyl group; and a copolymer obtained by copolymerizing an acrylic acid ester monomer. The present invention also provides the adhesive composition and an adhesive film using the same, a touch panel, and an electronic device. The adhesive composition of the present invention has characteristics of high flexibility and good cutting properties, durability, transparency, etc.
1 . An adhesive composition comprising:
a copolymer obtained by copolymerization of a C 2 to C 14 alkyl acrylic acid ester monomer, a hydroxyl group-containing acrylic acid ester monomer, and an acrylic acid ester monomer,
wherein the adhesive composition has a shear modulus from 15,000 Pa to 40,000 Pa, as measured at 60° C. using an ARES instrument.
2 . The adhesive composition according to claim 1 , wherein the hydroxyl group-containing acrylic acid ester monomer is present in an amount of 2 parts by weight to 60 parts by weight based on 100 parts by weight of the alkyl acrylic acid ester monomer.
3 . The adhesive composition according to claim 1 , wherein the acrylic acid ester monomer is present in an amount of 2 parts by weight to 70 parts by weight based on 100 parts by weight of the alkyl acrylic acid ester monomer.
4 . The adhesive composition according to claim 1 , wherein the alkyl acrylic acid ester monomer is selected from the group consisting of ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, t-butyl (meth)acrylate, sec-butyl (meth)acrylate, pentyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, n-octyl (meth)acrylate, isooctyl (meth)acrylate, isononyl (meth)acrylate, lauryl (meth)acrylate, and tetradecyl (meth)acrylate.
5 . The adhesive composition according to claim 1 , wherein the hydroxyl group-containing acrylic acid ester monomer is selected from the group consisting of 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 2-hydroxyethyleneglycol (meth)acrylate, and 2-hydroxypropyleneglycol (meth)acrylate.
6 . The adhesive composition according to claim 1 , wherein the acrylic acid ester monomer is isobornyl acrylate or isobornyl methacrylate.
7 . The adhesive composition according to claim 1 , further comprising:
0.01 parts by weight to 7.0 parts by weight of a curing agent based on 100 parts by weight of the alkyl acrylic acid ester monomer.
8 . The adhesive composition according to claim 1 , wherein the adhesive composition has an adhesive strength from 3000 On to 4000 On, as measured in accordance with ASTM D3330 modified.
9 . The adhesive composition according to claim 1 , wherein the adhesive composition has a shear modulus from 70000 Pa to 95000 Pa, as measured at 20° C. using an ARES instrument.
10 . The adhesive composition according to claim 1 , wherein the adhesive composition has a difference from 45000 Pa to 65000 Pa between a shear modulus measured at 20° C. and a shear modulus measured at 60° C., using an ARES instrument.
11 . The adhesive composition according to claim 1 , further comprising:
a coupling agent, a photoinitiator, a curing agent, and a molecular weight regulator.
12 . An adhesive film comprising:
an adhesive layer formed of the adhesive composition according to claim 1 ; and
release liners disposed on both surfaces of the adhesive layer, respectively.
13 . The adhesive film according to claim 12 , wherein the release liners have different release forces.
14 . The adhesive film according to claim 12 , wherein the adhesive layer has a thickness from 20 μm to 350 μm.
15 . A touch panel comprising an adhesive layer formed of the adhesive composition according to claim 1 .
16 . An electronic apparatus comprising the touch panel according to claim 15 .
17 . An adhesive film comprising:
an adhesive layer formed of the adhesive composition according to claim 7 ; and release liners disposed on both surfaces of the adhesive layer, respectively.
18 . An adhesive film comprising:
an adhesive layer formed of the adhesive composition according to claim 8 ; and release liners disposed on both surfaces of the adhesive layer, respectively.
19 . An adhesive film comprising:
an adhesive layer formed of the adhesive composition according to claim 9 ; and release liners disposed on both surfaces of the adhesive layer, respectively.
20 . An adhesive film comprising:
an adhesive layer formed of the adhesive composition according to claim 10 ; and release liners disposed on both surfaces of the adhesive layer, respectively.