IP Library Granted Patent US 9,169,378
Granted Patent B2
US 9,169,378 · App. 14/402,733 · Granted Oct 27, 2015

Polymer composition for blow moulding

Inventors: Isabelle Cermelli (Sausset les Pins, FR); Luc Marie Ghislain Dheur (Brussels, BE); Fabian Siberdt (Braine-le-Chateau, BE)
Assignee: INEOS EUROPE AG
C08L23/06C08L2205/025C08L2308/00
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Quick Facts
Patent No.
US 9,169,378
App. No.
14/402,733
Granted
Oct 27, 2015
Kind
B2
Abstract

A polyethylene composition is disclosed which comprises from 45 to 55 wt % of an ethylene polymer (A) having a density of at least 968 kg/m 3 , and from 55 to 45 wt % of an ethylene polymer (B) having a density of 920 to 955 kg/m 3 , wherein the composition has a density of 952 to 961 kg/m 3 , a high load melt index HLMI of 18-28 g/10 min, a ratio of HLMI/ML of 80-150, and a melt elastic modulus G′ (G″=3000) of 1200-1600 Pa, where HLMI and ML 2 are measured according to ISO1133 at a temperature of 190° C. under loads of 21.6 kg and 2.16 kg respectively.

Claims (17)

1. Polyethylene composition comprising from 45 to 55 wt % of an ethylene polymer (A) having a density of at least 968 kg/m 3 , and from 55 to 45 wt % of an ethylene polymer (B) having a density of 920 to 955 kg/m 3 , wherein the composition has a density of 952 to 961 kg/m 3 , a high load melt index HLMI of 18-28 g/10 min, a ratio of HLMI/MI 2 of 80-150, and a melt elastic modulus G′(G″=3000) of 1200-1600 Pa, where HLMI and MI 2 are measured according to ISO1133 at a temperature of 190° C. under loads of 21.6 kg and 2.16 kg respectively.

2. Polyethylene composition according to claim 1 , which has an HLMI of from 18 to 26.

3. Polyethylene composition according to claim 1 , which has an HLMI of from 19 to 25.

4. Polyethylene composition according to claim 1 , wherein the ratio HLMI/MI 2 is 85-140.

5. Polyethylene composition according to claim 1 , wherein the ratio HLMI/MI 2 is 85-130.

6. Polyethylene composition according to claim 1 , wherein the melt flow index MI 2 is between 0.1 g/10 min and 0.5 g/10 min.

7. Polyethylene composition according to claim 1 , wherein the melt flow index MI 2 is between 0.15 g/10 min and 0.45 g/10 min.

8. Polyethylene composition according to claim 1 , wherein the melt flow index MI 2 is between 0.2 g/10 min and 0.3 g/10 min.

9. Polyethylene composition according to claim 1 , which has a melt elastic modulus G′(G″=3000) of from 1250 to 1550 Pa.

10. Polyethylene composition according to claim 1 , which has a melt elastic modulus G′(G″=3000) is from 1300 to 1500 Pa.

11. Polyethylene composition according to claim 1 , which has a density of from 954 to 960 kg/m 3 .

12. Polyethylene composition according to claim 1 , which has a density of from 955 to 959 kg/m 3 .

13. Polyethylene composition according to claim 1 , which has a die swell ratio (DSR) as a function of shear rate (SR) satisfying the relationship DSR≧C.(SR) n where C=0.94 and n=0.094, when measured on a capillary rheometer using a Length/Diameter (L/D)=15/1 mm die at 190° C. over shear rates between 20 and 700 s −1 .

14. Polyethylene composition according to claim 1 , which has a die swell ratio equal to or greater than 1.44, when measured on a capillary rheometer using a Length/Diameter (L/D)=15/1 mm die at 190° C. at a shear rate of 100 s −1 .

15. Polyethylene composition according to claim 1 , which has a density between 954 to 959 kg/m 3 and an HLMI between 19 and 25 g/10 min, and comprises from 47 to 53 wt % of an ethylene polymer (A) having a density of between 970 and 974 kg/m 3 , and from 47 to 53 wt % of an ethylene polymer (B) having a density of between 940 and 950 kg/m 3 , the ratio of (A):(B) also being from 47:53 to 53:47.

16. Polyethylene composition according to claim 1 , which is in the form of a blow moulded article.

17. Polyethylene composition according to claim 1 , which is in the form of a blow moulded container.

Assignments (2)
SECURITY INTEREST Recorded May 4, 2017
From: INEOS TECHNOLOGIES USA LLC; INEOS EUROPE AG
To: BARCLAYS BANK PLC
Reel/Frame 042398/0916 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 21, 2014
From: CERMELLI, ISABELLE; DHEUR, LUC MARIE GHISLAIN; SIBERDT, FABIAN
To: INEOS EUROPE AG
Reel/Frame 034227/0758 →
Priority Claims (1)
EP 12170051 · May 30, 2012 · regional
Continuity (1)
Related Publication 20150159002A1 · Jun 11, 2015