Method of making a cBN material
A cBN material and a method of making a cBN material, the method including the steps of providing a powder mixture comprising cBN grains, aluminum and a Ti(CxNyOz)a powder, subjecting the powder mixture to a milling to form a powder blend, subjecting the powder blend to a forming operation to form a green body, subjecting the green body to a pre-sintering step, at a temperature between 650 to 950° C., to form a pre-sintered body, and subjecting the pre-sintered body to a HPHT operation to form the cBN material. For the Ti(CxNyOz)a powder, 0.05≤z≤0.4. In addition, a cBN material includes cBN grains, an Al2O3 phase, a binder phase of TiC, TiN and/or TiCN, W and Co, whereby a quotient Q is <0.25 of the cBN material.
1. A method of making a cBN material comprising:
providing a powder mixture comprising cBN grains, aluminum and a Ti(C x N y O z ) a powder;
subjecting the powder mixture to a milling operation to form a powder blend;
subjecting the powder blend to a forming operation to form a green body;
subjecting said green body to a pre-sintering step, at a temperature between about 650 to about 950° C., to form a pre-sintered body; and
subjecting said pre-sintered body to a HPHT operation to form the cBN material, wherein for said Ti(C x N y O z ) a powder, 0.9≤a≤1.1; 0.5≤x≤0.95; 0≤y≤0.3; and 0.05≤z≤0.4.
2. A method according to claim 1 , wherein the Ti(C x N y O z ) a powder is provided in an amount of 10 to 70 wt % of the total dry powder weight of the powder mixture.
3. A method according to claim 1 , wherein for the Ti(C x N y O z ) a powder, 0.5≤x≤0.95, 0.0≤y≤0.3; and 0.1≤z≤0.3.
4. A method according to claim 1 , wherein 0.7≤x≤0.95 and stoichiometric TiN is added in an amount so that TiN replaces the Ti(C x N y O z ) a powder by between 5 to 55 wt %.
5. A method according to claim 4 , wherein 0.7≤x≤0.95 and stoichiometric TiN is added in an amount so that TiN replaces the Ti(C x N y O z ) a powder by between 25 to 55 wt %.
6. A method according to claim 1 , wherein the aluminum in the powder mixture is elemental aluminum.
7. A method according to claim 1 , wherein aluminum is provided in an amount of 1 to 10 wt % of the total dry powder weight of the powder mixture.
8. A method according to claim 1 , wherein W is added such that the amount of W is 1 to 12 wt % of the cBN material, and Co is added such that the amount of Co is between 0.5 to 9 wt % of the cBN material, where the W/Co ratio is between 1.0 to 2.0.
9. A method according to claim 1 , wherein a part of the Ti(C x N y O z ) a powder is replaced by stoichiometric TiN, TiC and/or TiCN.
10. A method according to claim 1 , wherein a milling liquid is added to the powder mixture to form a slurry and wherein the milling operation is followed by a drying operation to form the powder blend.
11. A method according to claim 10 , wherein the drying operation is done by spray drying.
12. A method according to claim 1 , wherein the pre-sintering is done at a temperature of between about 850° C. to about 930° C.
13. A method according to claim 1 , wherein the HPHT operation is performed at a pressure of about 55 to about 75 kbar and a temperature from about 1300 to about 1600° C.
14. A method of making a cBN material comprising:
providing a powder mixture comprising cBN grains, elemental aluminum and a Ti(C x N y O z ) a powder;
subjecting the powder mixture to a milling operation to form a powder blend;
subjecting the powder blend to a forming operation to form a green body;
subjecting said green body to a pre-sintering step, at a temperature between about 650 to about 950° C., to form a pre-sintered body; and
subjecting said pre-sintered body to a HPHT operation to form the cBN material,
wherein for said Ti(C x N y O z ) a powder, 0.9≤a≤1.1, 0.5≤x≤0.95; 0.00≤y≤0.3; and 0.1≤z≤0.3.
15. A method according to claim 14 , wherein 0.7≤x≤0.95 and stoichiometric TiN is added in an amount so that TiN replaces the Ti(C x N y O z ) a powder by between 5 to 55 wt %.
16. A method according to claim 15 , wherein 0.7≤x≤0.95 and stoichiometric TiN is added in an amount so that TiN replaces the Ti(C x N y O z ) a powder by between 25 to 55 wt %.
17. A method of making a cBN material comprising:
providing a powder mixture comprising cBN grains, elemental aluminum and a Ti(C x N y O z ) a powder;
subjecting the powder mixture to a milling operation to form a powder blend;
subjecting the powder blend to a forming operation to form a green body;
subjecting said green body to a pre-sintering step, at a temperature between about 650 to about 950° C., to form a pre-sintered body; and
subjecting said pre-sintered body to a HPHT operation to form the cBN material,
wherein for said Ti(C x N y O z ) a powder, 0.9≤a≤1.1, 0.3≤x≤0.95; 0.00≤y≤0.5; and 0.05≤z≤0.3.
18. A method according to claim 17 , wherein 0.7≤x≤0.95 and stoichiometric TiN is added in an amount so that TiN replaces the Ti(C x N y O z ) a powder by between 5 to 55 wt %.
19. A method according to claim 18 , wherein 0.7≤x≤0.95 and stoichiometric TiN is added in an amount so that TiN replaces the Ti(C x N y O z ) a powder by between 25 to 55 wt %.