Processes for preparing lithium carbonate
There are provided methods for preparing lithium carbonate. For example, such methods can comprise reacting an aqueous composition comprising lithium hydroxide with CO 2 by sparging the CO 2 the said composition, thereby obtaining a precipitate comprising the lithium carbonate. The methods can also comprise inserting at least a portion of the precipitate into a clarifier and obtaining a supernatant comprising lithium bicarbonate and a solid comprising the lithium carbonate, separating the solid from the supernatant; and heating the supernatant at a desired temperature so as to at least partially convert the lithium bicarbonate into lithium carbonate.
1. A process for preparing lithium carbonate, said process comprising:
reacting an aqueous composition comprising lithium hydroxide with CO 2 by sparging said CO 2 into said composition, said sparging being carried out while pH is at least substantially maintained at a value of about 10 to about 11.5, thereby obtaining a slurry comprising said lithium carbonate;
inserting at least a portion of said slurry into a clarifier and obtaining a supernatant comprising lithium bicarbonate and a solid comprising said lithium carbonate, separating said solid from said supernatant; and
heating said supernatant at a temperature of at least 85° C. so as to at least partially convert said lithium bicarbonate into lithium carbonate.
2. The process of claim 1 , wherein said process comprises heating said supernatant at said temperature of at least 85° C. so as to at least partially convert said lithium bicarbonate into lithium carbonate and precipitate any dissolved lithium carbonate contained therein.
3. The process of claim 1 , wherein during said sparging, said pH is at least substantially maintained at a value of about 10.5 to about 11.5.
4. The process of claim 1 , wherein during said sparging, said pH is at least substantially maintained at a value of about 10.7 to about 11.3.
5. The process of claim 1 , wherein during said sparging, said pH is at least substantially maintained at a value of about 10.8 to about 11.2.
6. The process of claim 1 , wherein said supernatant is heated at a temperature of at least 91° C.
7. The process of claim 1 , wherein said supernatant is heated at a temperature of at least 95° C.
8. The process of claim 1 , wherein said supernatant is heated at a temperature of about 85° C. to about 105° C.
9. The process of claim 3 , wherein said supernatant is heated at a temperature of about 90° C. to about 100° C.
10. The process of claim 3 , wherein said supernatant is heated at a temperature of about 92° C. to about 98° C.
11. The process of claim 3 , wherein said supernatant is heated at a temperature of about 93° C. to about 97° C.
12. The process of claim 1 , wherein during said process said aqueous composition comprising lithium hydroxide is at least substantially maintained at a concentration of lithium hydroxide of about 30 to about 70 g/L.
13. The process of claim 3 , wherein during said process said aqueous composition comprising lithium hydroxide is at least substantially maintained at a concentration of lithium hydroxide of about 40 to about 60 g/L.
14. The process of claim 3 , wherein during said process said aqueous composition comprising lithium hydroxide is at least substantially maintained at a concentration of lithium hydroxide of about 48 to about 55 g/L.
15. The process of claim 13 , wherein said sparging is carried out at a temperature of about 15 to about 30° C.
16. The process of claim 1 , wherein during said process said supernatant, when being heated, is at least substantially maintained at a Li concentration of about 1 to about 10 g/L.
17. The process of claim 3 , wherein during said process said supernatant, when being heated, is at least substantially maintained at a Li concentration of about 2 to about 6 g/L.
18. The process of claim 15 , wherein during said process said supernatant, when being heated, is at least substantially maintained at a Li concentration of about 3 to about 5 g/L.
19. The process of claim 1 , wherein said lithium hydroxide is obtained by submitting an aqueous composition comprising a lithium compound to an electrodialysis or electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide, wherein during said electrodialysis or electrolysis, said aqueous composition comprising said lithium compound is at least substantially maintained at a pH having a value of about 9.5 to about 12.5.
20. The process of claim 1 , wherein said lithium hydroxide is obtained by submitting an aqueous composition comprising lithium sulphate to an electrolysis under conditions suitable for converting at least a portion of said lithium sulphate into lithium hydroxide, wherein during said electrolysis, said aqueous composition comprising lithium sulphate has a pH of greater than 7.