Dichromatic dye composition and application thereof

1. A dichromatic dye composition, comprising:

one or more compounds forming the dichromatic dye composition,

wherein, based on a total weight of the dichromatic dye composition, the dichromatic dye composition comprises:

(1) 0%-50% by weight of one or more compounds of formula (I)

(2) 5%-85% by weight of one or more compounds of formula (II)

(3) 0%-95% by weight of one or more compounds of formula (III)

wherein:

R 1 and R 3 are the same or different, and are independently selected from the group consisting —H, —F, —NO 2 , —NH 2 , —SO 2 R, —SR, C 1-12 alkyl and C 1-12 alkoxy, in which one or more H of the C 1-12 alkyl and the C 1-12 alkoxy can be independently substituted by F, and H or the —NH 2 can be each independently substituted by C 1-12 alkyl;

R 2 is selected from the group consisting of —H, —F, —NO 2 , —NH 2 , —SO 2 R, —SR, C 1-12 alkyl and C 1-12 alkoxy, in which one or more H of the C 1-12 alkyl and the C 1-12 alkoxy can be independently substituted by F, and —H of the —NH 2 can be each, independently substituted by Ra or Ra′; the Ra and Ra′ are the same or different, and independently are C 1-10 alkyl, in which one or more H of the C 1-10 alkyl can be independently substituted by F;

R 4 is selected from the group consisting of —H, —F, —NO 2 , —NH 2 , —SO 2 R, —SR, C 1-12 alkyl and C 1-12 alkoxy; in which one or more H of the C 1-12 alkyl and the C 1-12 alkoxy can be independently substituted by F, and H of the —NH 2 can be each, independently, substituted by Rb or Rb′; the Rb and Rb′ are the same or different, and independently are C 1-10 alkyl, in which one or more H of the C 1-10 alkyl can be independently substituted by F;

R is C 1-12 alkyl with or without halogenation;

Z 1 , Z 2 , Z 3 , Z 4 , Z 5 and Z 6 are the same or different, and are independently selected from the group consisting of single bond, —COO—, —OCO—, —N═N—, —CH═N—, —CH═CH—, —CF═CF—, —CF 2 O— and —C≡C—;

L 1 , L 2 , L 3 and L 4 are the same or different, and are independently selected from the group consisting of —H, —F, C 1-12 alkyl, and C 1-12 alkoxy, in which one or more H of the C 1-12 alkyl, and the C 1-12 alkoxy can be independently substituted by F;

L 5 , L 6 , L 7 , L 8 , L 9 and L 10 are the same or different, and are independently selected from the group consisting of hydroxyl, amino, C 1-15 alkyl, C 1-15 alkoxy,

in which H of the hydroxyl and the amino can be each, independently, substituted by

and one or more H of the C 1-15 alkyl and the C 1-15 alkoxy can be independently substituted by F or Cl; R n is selected from the group consisting of C 1-15 alkyl or alkoxy and C 2-14 alkenyl or alkynyl, in which one or more H of the C 1-15 alkyl or alkoxy and the C 2-14 alkenyl can be each, independently, substituted by F or Cl;

are the same or different, and each, independently, are selected from the group consisting of

in which one or more nonadjacent —CH 2 — of the

can be independently replaced by O, one or more H of the

can be independently substituted by halogen or C 1-10 alkyl; and

a and b each are 0, 1 or 2;

an absorbance curve of a guest-host liquid crystal composition containing the dichromatic dye composition within a wavelength range of 420-680 nm having the following characteristics:

2≦( T 1 +T 2 )/Δ T≦ 10;  a.

| T 1 −T 2 |≦0.5;  b.

0<Δ T≦ 0.2;  c.

wherein:

T 1 is a difference between a transmittance to light having a wavelength of 420 nm and a minimum transmittance on a transmittance curve;

T 2 is a difference between the transmittance at a wavelength of 680 nm and a minimum transmittance on the transmittance curve;

ΔT is a difference between the maximum transmittance and the minimum transmittance on the transmittance curve within the wavelength range of 420-680 nm.

2. The dichromatic dye composition according to claim 1 , wherein any guest-host liquid crystal composition which is formed by the dichromatic dye composition and a different host liquid crystal, has said characteristics, in which the dichromatic dye composition and the host liquid crystal are soluble with each other.

3. The dichromatic dye composition according to claim 1 , wherein the compound of formula (I) is one or more compounds selected from the group consisting of the following compounds:

wherein:

R 1 is selected from the group consisting of —H, —F, —NO 2 , —NH 2 , —SO 2 R, —SR, C 1-8 alkyl and C 1-8 alkoxy; in which one or more H of the C 1-8 alkyl and the C 1-8 alkoxy can be independently substituted by F, and H of the —NH 2 can be each, independently, substituted by C 1-8 alkyl;

R 2 is selected from the group consisting of —H, —F, —SO 2 R, C 1-8 alkyl and C 1-8 alkoxy; in which one or more H of the C 1-8 alkyl and the C 1-8 alkoxy can be independently substituted by F;

R is C 1-10 alkyl with or without fluoro-substitution;

Ra and Ra′ can be same or different, and each, independently, are C 1-8 alkyl, in which one or more H of C 1-8 alkyl can be independently substituted by F;

L 1 and L 2 can be same or different, and each, independently, are selected from the group consisting of —H, —F, C 1-6 alkyl and C 1-6 alkoxy; in which one or more H of the C 1-6 alkyl and the C 1-6 alkoxy can be independently substituted by F;

in which one or more H of the

can be independently substituted by F or C 1-6 alkyl.

4. The dichromatic dye composition according to claim 1 , wherein that the compound of formula (II) is one or more compounds selected from the group consisting of following compounds:

wherein:

R 3 is selected from the group consisting of —H, —F, —NO 2 , —NH 2 , —SO 2 R, —SR, C 1-8 alkyl and C 1-8 alkoxy; in which one or more H of the C 1-8 alkyl and the C 1-8 alkoxy can be independently substituted by F, and H of the —NH 2 can each, independently, be substituted by C 1-8 alkyl;

R 4 is selected from the group consisting of —H, —F, —SO 2 R, C 1-8 alkyl and C 1-8 alkoxy; in which one or more H of the C 1-8 alkyl and the C 1-8 alkoxy can be independently substituted by F;

R is C 1-10 alkyl with or without fluoro-substitution;

Rb and Rb′ are the same or different, and each, independently, are C 1-8 alkyl, in which one or more H of C 1-8 alkyl can be independently substituted by F;

L 3 and L 4 are the same or different, and each, independently, are selected from the group consisting of —H, —F, C 1-6 alkyl and C 1-6 alkoxy; in which one or more H of the C 1-6 alkyl and the C 1-6 alkoxy can be independently substituted by F;

in which one or more H of the

can be independently substituted by F or C 1-6 alkyl.

5. The dichromatic dye composition according to claim 1 , wherein that the compound of general formula (III) is one of more compounds selected from the group consisting of following compounds:

wherein:

R 5 , R 6 , R 7 , R 8 , R 9 and R 10 are the same or different, and each, independently, are selected from the group consisting of C 1-10 alkyl, C 1-10 alkoxy, C 2-10 alkenyl and C 2-10 alkynyl.

6. The dichromatic dye composition according to claim 1 , wherein the compound of formula (I)

comprises 0%-40% of the dichromatic dye composition; the compound of formula (II)

comprises 10%-80% of the dichromatic dye composition; and the compound of formula (III)

comprises 0%-90% of the dichromatic dye composition.

7. The dichromatic dye compositions according to claim 1 , wherein, based on a total weight of the dichromatic dye composition, the composition comprises:

38.1% of the compound of formula (II-1)

33.3% of the compound of formula (III-1)

and

28.6% of the compound of formula (III-8)

8. The dichromatic dye compositions according to claim 1 , wherein, based on a total weight of the dichromatic dye composition, the composition comprises:

20.0% of the compound of formula (II-1)

45.0% of the compound of formula (III-5)

and

35.0% of the compound of formula (III-4)

9. The dichromatic dye compositions according to claim 1 , wherein, based on a total weight of the dichromatic dye composition, the composition comprises:

30.0% of the compound of formula (I-10)

15.0% of the compound of formula (II-13)

and

55.0% of the compound of formula (II-3)

10. A guest-host liquid crystal composition, comprising:

a host liquid crystal;

the dichromatic dye composition according to claim 1 in said host liquid crystal;

said dichromatic dye composition accounting for 0.1-10% of a total weight of the guest-host liquid crystal composition.

11. The guest-host liquid crystal composition according to claim 10 , wherein said dichromatic dye composition accounts for 0.5-5% of the total weight of the guest-host liquid crystal composition.

12. The guest-host liquid crystal composition according to claim 11 , which further comprises a chiral dopant accounting for 0-5% of the total weight of the guest-host liquid crystal composition.

13. A liquid crystal display device, comprising the guest-host liquid crystal composition according to claim 10 .

14. In a method of manufacturing electrode substrates, employing the liquid crystal display device according to claim 13 in the manufacturing of the electrode substrates.