Tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer
View Patent ↗Purpose: To provide a melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer with excellent durability without causing an excessive decrease of the melt flow rate and an increase of the perfluoro(alkyl vinyl ether) content. Solution means: A melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, which is characterized in that in a parallel plate mode of a dynamic viscoelasticity measuring device, when the temperature is raised from −40° C. to 200° C. at 5° C./min while fixing the measuring frequency to 1 Hz, the slope (Δ tan δ/ΔT) of the loss tangent (tan δ) measured between two arbitrary points in a range of 50-75° C. and at a temperature difference of 3° C. or higher is always in a range of 0.0005-0.0030, and its preparation method.
1. A melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, characterized in that in a parallel plate mode of a dynamic viscoelasticity measuring device, when the temperature is raised from −40° C. to 200° C. at 5° C./min while fixing the measuring frequency to 1 Hz, the slope (Δ tan δ/ΔT) of the loss tangent (tan δ) measured between two arbitrary points in a range of 50-75° C. and at a temperature difference of 3° C. or higher is always in a range of 0.0005-0.0030, said copolymer being further characterized in that the flex life ratio of said copolymer is 1 or greater, wherein said flex life ratio is represented by the expression [FL meas]/[FL calc], wherein: FL meas is the measured flex life of said copolymer, and wherein FL calc is given by the expression
Ln[FL calc]= B 1− B 2×Ln[MFR]+ B 3×Ln[PAVE],
wherein [MFR] is the measured melt flow rate of said copolymer in g/10 min, and [PAVE] is the measured weight percent content of said perfluoro(alkyl vinyl ether) in said copolymer, and wherein coefficients B1, B2, and B3 depend on said perfluoro(alkyl vinyl ether) comonomer and said copolymer melt flow rate as follows: when said perfluoro(alkyl vinyl ether) of said copolymer is perfluoro(ethyl vinyl ether), then B1=9.446, B2=1.358 and B3=3.552; when said perfluoro(alkyl vinyl ether) of said copolymer is perfluoro(propyl vinyl ether) and said copolymer melt flow rate is less than 5 g/10 min, then B1=12.983, B2=3.322, B3=2.406; and when said perfluoro(alkyl vinyl ether) of said copolymer is perfluoro(propyl vinyl ether) and said copolymer melt flow rate is 5 g/10 min or more, then B1=12.07, B2=2.48, B3=3.22.
2. The melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer of claim 1 , characterized in that the perfluoro(alkyl vinyl ether) is a compound represented by the following Chemical formula (1) or (2):
CF 2 ═CF(OCF 2 CF(CF 3 )) n —O—(CF 2 ) m CF 3 Chemical formula 1:
wherein n represents an integer of from 0-4, and m represents an integer of from 0-7,
CF 2 ═CF(OCF 2 CF(CF 3 )) q —O—CF 2 —CF(CF 3 )—CF 3 , Chemical formula 2:
wherein q represents an integer of from 0-3.
3. The melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer of claim 1 , characterized in that the perfluoro(alkyl vinyl ether) is perfluoro(ethyl vinyl ether) or perfluoro(propyl vinyl ether).
4. The melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer of claim 1 , characterized in that the perfluoro(alkyl vinyl ether) content of the melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer is 1.0-50 wt %.
5. The melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer of claim 1 , characterized in that the melt flow rate of the melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer is 1-80 g/10 min.
6. A molded product that is obtained by molding the melt-moldable tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer of claim 1 .