METHOD OF PURIFYING CALCIUM FLUORIDE
The present invention provides a method for purifying an inorganic compound, in particular calcium fluoride. The method includes contacting (e.g., washing) the inorganic compound with an aqueous solution, in particular hydrochloric acid.
1 . A method for purifying an inorganic compound comprising at least one of calcium chloride, calcium bromide, calcium iodide, beryllium fluoride, magnesium fluoride, strontium fluoride, barium fluoride and calcium fluoride, the inorganic compound comprising at least about 100 ppm impurities, the method comprising washing the inorganic compound with an aqueous solution comprising an acid.
2 . The method of claim 1 , wherein the inorganic compound is an amorphous powder or a crystalline solid.
3 - 4 . (canceled)
5 . The method of claim 1 , wherein the inorganic compound comprises calcium fluoride (CaF 2 ).
6 . The method of claim 1 , wherein the inorganic compound has a solubility in water, at 20° C., of less than about 0.0020 g/100 mL.
7 . (canceled)
8 . The method of claim 1 , wherein the inorganic compound comprises up to about 750 ppm impurities.
9 . The method of any one of claims claim 1 , wherein the impurities of the inorganic compound comprise at least one of phosphorous-containing impurities, aluminum-containing impurities, iron-containing impurities, and boron-containing impurities.
10 . The method of any claim 1 , wherein the starting inorganic compound comprises at least about 100 ppm phosphorous-containing impurities.
11 . (canceled)
12 . The method of claim 7 , wherein at least one of the impurities has a solubility in water, at 20° C., of greater than about 0.0025 g/100 mL.
13 . The method of claim 1 , wherein the washing of the inorganic compound with the aqueous solution comprises mixing the inorganic compound and the aqueous solution.
14 . The method of claim 1 , further comprising washing the purified inorganic compound with a second aqueous solution, to remove acid from the purified inorganic compound.
15 - 17 . (canceled)
18 . The method of claim 1 , wherein the acid comprises at least one mineral acid.
19 . The method of claim 1 , wherein the acid comprises hydrogen chloride (HCl).
20 - 22 . (canceled)
23 . The method of claim 1 , wherein the purified inorganic compound comprises less than about 10 ppm phosphorous-containing impurities.
24 . (canceled)
25 . The method of claim 1 , wherein the purified inorganic compound is at least about 99.99 wt. % pure.
26 - 28 . (canceled)
29 . A method for purifying crystalline calcium fluoride (CaF 2 ) containing phosphorous-containing impurities, the method comprising washing the crystalline calcium fluoride (CaF 2 ) with an aqueous solution comprising acid, to remove at least some of the phosphorous-containing impurities from the crystalline calcium fluoride (CaF 2 ).
30 . The method of claim 29 , wherein the crystalline calcium fluoride (CaF 2 ) comprises at least about 100 ppm phosphorous-containing impurities.
31 . The method of claim 29 , wherein the aqueous solution acid is aqueous hydrochloric acid.
32 . The method of claim 29 , wherein the the acid is about 5-20 wt. % mineral acid.
33 . The method of claim 29 or 30 , wherein the aqueous solution is about 5-20 wt. % aqueous hydrochloric acid.
34 . The method of claim 29 , wherein the purified inorganic compound comprises up to about 10 ppm phosphorous-containing impurities.