Method for preparing emulsifiable solid agrochemical composition containing inorganic salt
The present invention relates to a method for preparing an emulsifiable solid agrochemical composition which contains an inorganic salt and which can be used as an agrochemical emulsion. The preparation method according to the present invention has the advantage that, because there is no need for a step of heating and evaporating a solvent or water, it is possible to use a surfactant or active ingredient that has a low boiling point or breaks down drastically at a high temperature, and, due to the solid-phase form, it is possible to minimise the amount that sticks to a container as there is no need to use a special synthetic resin or glass bottle that entails high packaging costs. Also, a granular emulsifier (EG) or a powdery emulsifier (EP) produced by means of the method according to the present invention can be further diluted in water before use so as to form common emulsion (EC) emulsified particles (0.1 μm to 100 μm) to transparent microemulsion particles (0.001 μm to 1 μm, or 1 nm to 1000 nm), and thus the emulsion size can be freely modified so as to maximise the activity of the agrochemical component in accordance with the characteristics of a crop or an insect pest.
1. A method for preparing an emulsifiable solid agrochemical composition without heating and evaporating a solvent or water, comprising:
(1) mixing an agrochemical active ingredient and a surfactant to prepare a liquid emulsifiable concentrate; and
(2) adsorbing the liquid emulsifiable concentrate onto an inorganic salt;
wherein the inorganic salt is selected from the group consisting of sodium carbonate (Na 2 CO 3 ), anhydrous sodium carbonate, sodium hydrogen carbonate (NaHCO 3 ), sodium percarbonate (2Na 2 CO 3 .3H 2 O 2 ), calcium chloride (CaCl 2 ), sodium phosphate (Na 2 HPO 4 ), anhydrous sodium phosphate, potassium carbonate (K 2 CO 3 ), anhydrous potassium carbonate, potassium phosphate (K 3 PO 4 ), anhydrous potassium phosphate, sodium sulfate (Na 2 SO 4 ), anhydrous sodium sulfate, ammonium persulfate ((NH 4 ) 2 S 2 O 8 ), and a mixture thereof;
wherein the inorganic salt is used in an amount of 60 to 95% by weight, based on the total amount of the composition.
2. The method of claim 1 , wherein the agrochemical active ingredient is a pesticide, a fungicide or a herbicide.
3. The method of claim 1 , wherein the surfactant is a non-ionic surfactant, or an ionic surfactant.
4. The method of claim 1 , wherein the inorganic salt is sodium carbonate or potassium carbonate.
5. The method of claim 1 , further comprising:
dissolving the agrochemical active ingredient in a solvent before mixing the agrochemical active ingredient with the surfactant when the agrochemical active ingredient is in a solid phase.
6. The method of claim 5 , wherein the solvent is selected from the group consisting of an aliphatic paraffin oil, an aromatic solvent, a chlorinated hydrocarbon, an alcohol, a ketone, N-methyl pyrrolidone, a carbonate, an ether, a vegetable oil, a methylated vegetable oil, petroleum oil, a sugar fatty acid ester, and a mixture thereof.
7. The method of claim 1 , wherein the inorganic salt is selected from potassium carbonate (K 2 CO 3 ) and anhydrous potassium carbonate.
8. The method of claim 1 , wherein the inorganic salt has an oil absorbency of 10% to 47%.