Display device, method for manufacturing same, polyimide film for display device supporting bases, and method for producing polyimide film for display device supporting bases
View Patent ↗Provided is a display device that can be made thin, lightweight, and flexible, has no problems of cracks and peeling caused by thermal stress, and is excellent in dimension stability and the like. The display device includes: a supporting base including a polyimide film; and a gas barrier layer formed on the supporting base, in which the polyimide film has a transmittance of 80% or more in a wavelength region of from 440 nm to 780 nm, and a coefficient of thermal expansion of 15 ppm/K or less, and has a difference in coefficient of thermal expansion from the gas barrier layer of 10 ppm/K or less.
1. A manufacturing method for a display device,
the manufacturing method comprising:
applying a resin solution of polyimide or a polyimide precursor onto a base substrate so that a thickness of a polyimide film becomes 50 μm or less;
forming the polyimide film on the base substrate by completing heat treatment;
forming a stress relaxation layer for preventing stretching of the polyimide film on the polyimide film;
removing the base substrate under a state in which the polyimide film and the stress relaxation layer are laminated; and
forming a member for a display device,
the polyimide film comprising a single polyimide layer or a plurality of polyimide layers comprising a main polyimide layer containing polyimide having 70 mol % or more of a structural unit represented by the following general formula (1):
General formula
in the formula (1), Ar 1 represents a tetravalent organic group having an aromatic ring, and Ar 2 represents a divalent organic group represented by the following general formula (2) or (3),
General formula
in the general formula (2) or the general formula (3), R 1 to R 8 each independently represent a hydrogen atom, a fluorine atom, an alkyl group or alkoxy group having 1 to 5 carbon atoms, or a fluorine-substituted hydrocarbon group, and at least one of R 1 to R 4 in the general formula (2) and at least one of R 1 to R 8 in the general formula (3) each represent a fluorine atom or a fluorine-substituted hydrocarbon group.
2. A display device obtained by using the method according to claim 1 .
3. A production method for a polyimide film for a display device supporting base,
the production method comprising:
applying a resin solution of polyimide or a polyimide precursor onto a base substrate so that a thickness of a polyimide film becomes 50 μm or less;
forming the polyimide film on the base substrate by completing heat treatment;
forming a stress relaxation layer for preventing stretching of the polyimide film on the polyimide film; and
removing the base substrate under a state in which the polyimide film and the stress relaxation layer are laminated,
the polyimide film comprising a single polyimide layer or a plurality of polyimide layers comprising a main polyimide layer containing polyimide having 70 mol % or more of a structural unit represented by the following general formula (1):
General formula
in the formula (1), Ar 1 represents a tetravalent organic group having an aromatic ring, and Ar 2 represents a divalent organic group represented by the following general formula (2) or (3):
General formula
in the general formula (2) or the general formula (3), R 1 to R 8 each independently represent a hydrogen atom, a fluorine atom, an alkyl group or alkoxy group having 1 to 5 carbon atoms, or a fluorine-substituted hydrocarbon group, and at least one of R 1 to R 4 in the general formula (2) and at least one of R 1 to R 8 in the general formula (3) each represent a fluorine atom or a fluorine-substituted hydrocarbon group.
4. A production method for a polyimide film for a display device supporting base according to claim 3 , wherein the base substrate comprises glass.
5. A polyimide film for a display device supporting base obtained by using the method according to claim 3 .