Handle for semiconductor-on-diamond wafers and method of manufacture
Methods for mounting and dismounting thin and/or bowed semiconductor-on-diamond wafers ( 401 ) to a carrier ( 407 ) are disclosed that flatten said wafers and provide mechanical support to enable efficient semiconductor device processing on said semiconductor-on-diamond wafers.
1. A composite wafer comprising:
a semiconductor-on-diamond wafer comprising at least one layer of single-crystal semiconductor and at least one layer of diamond;
a carrier plate that includes diamond material; and
an adhesive disposed between said semiconductor-on-diamond wafer and said carrier plate;
wherein said at least one layer of diamond is proximal to said carrier plate,
wherein said carrier plate comprises a material having a coefficient of linear thermal expansion a at 20° C. in at least one plane of no more than 10.0×10 −6 K −1 ,
wherein said adhesive comprises a material having a melting point higher than 1000° C.,
wherein said adhesive is capable of withstanding a temperature change of at least 900° C. in no more than 1.5 minutes while maintaining bonding between the semiconductor-on-diamond wafer and the carrier plate,
wherein an exposed surface of single-crystal semiconductor has a surface flatness of lower than 30 μm over a total area of the exposed surface of single-crystal semiconductor,
wherein the composite wafer has a bow of no more than 30 μm over the total area of the composite wafer,
wherein the composite wafer has a thickness variation of no more than 30 μm over the total area of the composite wafer,
wherein the composite wafer has a longest linear dimension of at least 120 mm, and
wherein said at least one layer of single-crystal semiconductor comprises at least one semiconductor selected from the group containing gallium nitride, aluminum nitride, and indium nitride.
2. A composite wafer according to claim 1 , wherein the coefficient of linear thermal expansion a at 20° C. of the material of said carrier plate is no more than 8.0×10 −6 K −1 .
3. A composite wafer according to claim 1 , wherein said carrier plate is formed of a diamond composite material or a CVD diamond wafer.
4. A composite wafer according to claim 1 , wherein said adhesive is porous.
5. A composite wafer according to claim 1 , wherein said adhesive comprises a material having a coefficient of linear thermal expansion a at 20° C. in at least one plane of no more than 10.0×10-6 K-1.
6. A composite wafer according to claim 1 , wherein the melting point of the material of said adhesive is at least 1400° C.
7. A composite wafer according to claim 1 , wherein said adhesive is chemical resistant to one, more, or all of: HF; HCl; H 2 SO 4 ; HNO 3 ; KOH; H 2 O 2 ; Tetramethylammonium hydroxide (TMAH); Acetone; Isopropyl Alcohol (IPA); Methanol; Methylene Chloride; N-Methyl-2-pyrrolidone (NMP, 1165); Methyl Isobutyl Ketone (MIBK); and Methyl Ethyl Ketone (MEK).
8. A composite wafer according to claim 1 , wherein said adhesive is a ceramic adhesive.
9. A composite wafer according to claim 8 , wherein said ceramic adhesive comprises boron nitride.
10. A composite wafer according to claim 1 , wherein the surface flatness of the exposed surface of single-crystal semiconductor is lower than 20 μm over a total area of the exposed surface of single-crystal semiconductor.
11. A composite wafer according to claim 1 , wherein the bow of the composite wafer is no more than 20 μm over a total area of the composite wafer.
12. A composite wafer according to claim 1 , wherein the thickness variation of the composite wafer is no more than 20 μm over the total area of the composite wafer.
13. A composite wafer according to claim 1 , wherein the composite wafer has a tilt of no more than 30 μm over the total area of the composite wafer, wherein the tilt corresponds to a variation in edge height around the composite wafer when the composite wafer is laid on a flat surface.
14. A composite wafer according to claim 1 , wherein said semiconductor-on-diamond wafer has thickness less than 200 μm and said flat carrier plate has a thickness larger than 400 μm.
15. A composite wafer according to claim 1 , wherein the adhesive has a beveled edge.
16. A composite wafer according to claim 1 , further comprising a sealant configured to seal areas on said composite wafer where said adhesive would otherwise be exposed.