Method for joining ceramic bodies by means of an active hard solder, or braze, assembly having at least two ceramic bodies joined with one another, especially a pressure measuring cell

1 - 20 . (canceled)

21 . An assembly, comprising:

a first ceramic body; and

a second ceramic body, wherein:

said first ceramic body and said second ceramic body are connected by means of a joint, said joint containing an active hard solder, or braze;

the active hard solder, or braze, has a continuous core volume, which is spaced from said first ceramic body and from said second ceramic body, in each case, by at least 1 μm, especially at least 2 μm;

said joint has a first bounding layer and a second bounding layer, which border on said first ceramic body, respectively said second ceramic body; and

said continuous core volume, which includes at least 50% of the volume of said joint is free of crystalline phases of size greater than 6 μm, especially greater than 4 μm, preferably greater than 2 μm.

22 . An assembly, comprising:

a first ceramic body; and

a second ceramic body, wherein:

said first ceramic body and said second ceramic body are connected by means of a joint, said joint contains an active hard solder, or braze;

the active hard solder, or braze, averaged over a continuous core volume, which is spaced from said first ceramic body and from said second ceramic body, in each case, by at least 1 μm, especially at least 2 μm, has an average composition C K having a liquidus temperature T l (C K ),

wherein C K :=(c K1 , . . . , c KN ), wherein |C K |=1; and

the c Ki are the stoichiometric fractions of the components K i i=1, . . . , N of the average composition of said active hard solder, or braze, in said core volume;

said joint has a first bounding layer and a second bounding layer, which border on said first ceramic body, respectively on said second ceramic body;

at least one of said bounding layers, which lies outside of said core volume, has an average composition C B having a liquidus temperature T l (C B ), which lies not less than 20 K, preferably not less than 40 K, and especially preferably not less than 80 K under the liquidus temperature T l (C K ) of the average composition C K of the core volume, wherein C B :=(c B1 , . . . , c BN ), wherein |C B |=1, and wherein the c Bi are the stoichiometric fractions of the components K i i=1, . . . , N of the average composition of the active hard solder, or braze, in said bounding layer.

23 . The assembly as claimed in claim 21 , wherein:

at least one bounding layer has a thickness of no more than 3 μm, especially no more than 2 μm and preferably no more than 1 μm.

24 . The assembly as a claimed in claim 21 , wherein:

said joint is ring-shaped; and

said core volume is defined by a body of revolution, which is formed by rotation of a convex polygon, especially a rectangle, about the principal axis of revolution of said ring-shaped joint.

25 . The assembly as claimed in claim 22 , wherein:

said liquidus temperature rises from T l (C B ) to the liquidus temperature T l (C K ) monotonically with change of composition from C B to C K .

26 . The assembly as claimed in claim 22 , wherein:

the composition C B has a liquidus temperature T l (C B ), which lies no more than 300 K, especially no more than 150 K, and preferably no more than 50 K above the liquidus temperature T l (C e ) of the eutectic point, respectively the nearest intersection with a eutectic valley having a composition C e in the composition space; and

C e :=(c e1 , . . . , c eN ), wherein |C e |=1, and wherein the c ei are the stoichiometric fractions of the components K i with i=1, . . . , N at the eutectic point, respectively a nearest intersection with a eutectic valley.

27 . The assembly as claimed in claim 22 , wherein:

the alloy of said joint has at the eutectic point, respectively at the nearest intersection with a eutectic valley in the composition space, a composition C e , wherein C e :=(c e1 , . . . , c eN ), wherein |C e |=1, wherein the c ei are the stoichiometric fractions of the components K i with i=1, . . . , N at the eutectic point, respectively at the nearest intersection with a eutectic valley;

the difference between the composition C e and the composition C B is describable with a normalized vector difference D eB , wherein: C e =C B +a eB *D eB , with |D eB |=1;

the difference between the composition C K and the composition C B is describable with a normalized vector difference D KB , wherein: C K =C B +a KB *D KB , with |D KB |=1, wherein a eB and a KB are positive scalars, and for the scalar product s eK :=D eB ·D KB :

s eK <0, especially s eK <−0.5, preferably s eK <−0.8.

28 . The assembly as claimed in claim 22 , wherein:

the composition C K of the core volume contains metals, which also the composition C B of the bounding layer contains.

29 . The assembly as claimed in claim 21 , wherein:

said first ceramic body and/or said second ceramic body comprise/comprises Al 2 O 3 .

30 . The assembly as claimed in claim 22 , wherein:

said active hard solder, or braze, comprises Zr, Ni and Ti.

31 . The assembly as claimed in claim 30 , wherein:

the composition C K contains essentially zirconium and nickel, for example, in a stoichiometric ratio of, for instance, 3 to 1; and

the zirconium fraction amounts to, for example, 76 atom-% and the nickel fraction, for example, 24 atom-%.

32 . The assembly as claimed in claim 22 , wherein:

the bounding layer has a composition C B , which comprises, for instance, 42 to 52 atom-% Zr, 23 to 28 atom-% Ni and 24 to 30 atom-% Ti;

in given cases, Al diffuses in; and

in cases where Al is present, especially the titanium fraction is reduced.

33 . The assembly as claimed in claim 21 , wherein:

said two bounding layers of the joint have the composition C B .

34 . A pressure measuring cell, comprising:

an assembly including a first ceramic body; and a second ceramic body, wherein: said first ceramic body and said second ceramic body are connected by means of a joint, said joint containing an active hard solder, or braze; the active hard solder, or braze, has a continuous core volume, which is spaced from said first ceramic body and from said second ceramic body, in each case, by at least 1 μm, especially at least 2 μm; said joint has a first bounding layer and a second bounding layer, which border on said first ceramic body, respectively said second ceramic body; and said continuous core volume, which includes at least 50% of the volume of said joint is free of crystalline phases of size greater than 6 μm, especially greater than 4 μm, preferably greater than 2 μm, wherein:

said first ceramic body is a membrane body of a measuring membrane of the pressure measuring cell;

said second ceramic body is a platform of the pressure measuring cell; and

said platform and said measuring membrane are joined pressure-tightly with one another by means of said joint, which is ring-shaped.

35 . A method for manufacturing an assembly, comprises a

first ceramic body and a second ceramic body, wherein the first ceramic body and the second ceramic body are to be connected by means of an active hard solder, or braze, the method comprises the steps of:

providing the active hard solder, or braze, between the ceramic bodies;

the active hard solder, or braze, has, averaged over a continuous core volume, an average composition C K0 having a liquidus temperature T l (C K0 ), wherein C K0 :=(c K01 , . . . , c K0N ), wherein |C K0 |=1, and wherein the c Ki are the stoichiometric fractions of the components K i i=1, . . . , N of the average composition of the active hard solder, or braze, in the core volume;

the active hard solder, or braze, has, on at least one of its surfaces facing the ceramic bodies, a bounding layer having an average composition C B0 , wherein the composition C B0 has a liquidus temperature T l (C B0 ), which lies not less than 20 K, preferably not less than 40 K, and especially preferably not less than 80 K, under the liquidus temperature T l (C H0 ) of the average composition C K0 of the main volume, wherein C B0 :=(c B01 , . . . , c B0N ), wherein |C B0 |=1, and wherein the c B0i are the stoichiometric fractions of the components K i i=1, . . . , N of the average composition of the active hard solder, or braze, in the bounding layer; and

heating the ceramic bodies and the active hard solder, or braze, in a vacuum soldering, brazing process up to melting of the composition C B0 , wherein the melt of the bounding layer mixes in the transition to the core volume with the material of the core volume, whereby the liquidus temperature of the bounding layer is increased, so that the bounding layer at least partially isothermally solidifies or becomes more viscous.

36 . The method as claimed in claim 35 , wherein:

the providing of the active hard solder, or braze, includes a solder preform, which has the composition C K0 , coated by means of gas phase deposition, for example, by sputtering, at least on one surface, preferably on two oppositely lying surfaces, with a bounding layer, which has the composition C B0 .

37 . The method as claimed in claim 35 , wherein:

the providing of the active hard solder, or braze, includes at least one surface section of a ceramic body, especially two oppositely lying surface sections of the two ceramic bodies, respectively, coated with a bounding layer, which has the composition C B0 , and

the coating occurs, for example, by gas phase deposition, especially sputtering.

38 . The method as a claimed in claim 37 , wherein:

there is arranged between the ceramic bodies provided with the bounding layer a solder preform, which has a core volume with the composition C K0 , and which, in given cases, is coated with a bounding layer of composition C B0 .

39 . The method as claimed in claim 35 , wherein:

a composition K K0 comprises Zr and Ni in a stoichiometric ratio of 3 to 1, for example, 20 atom-% to 30 atom-% Ni and remainder Zr, especially, for instance, 22 atom-% to 26 atom-% Ni, preferably 24 atom-% Ni.

40 . The method as claimed in claim 35 , wherein:

the composition C B0 comprises, for instance, 42 to 52 atom-% Zr, 23 to 28 atom-% Ni and 24 to 30 atom-% Ti, for example, 45 to 49 atom-% Zr, 24.5 to 27 atom-% Ni and 26 to 29.5 atom-% Ti, and preferably 47 atom-% Zr, 26 atom-% Ni and 27 atom-% Ti.