Metal nanoparticle-graphene composites and methods for their preparation and use
View Patent ↗Methods of forming metal nanoparticle-graphene composites are provided. The methods can include mixing a metal precursor with graphite oxide in the presence of a liquid medium to form a metal precursor-graphite oxide mixture, and exfoliating the graphite oxide and reducing the metal precursor in the metal precursor-graphite oxide mixture to deposit metal nanoparticles on a first major surface of a graphene sheet formed by exfoliation of the graphite oxide.
1. A method to form a metal nanoparticle-graphene composite, the method comprising:
mixing a metal precursor with graphite oxide in presence of a liquid medium to form a metal precursor-graphite oxide mixture;
exfoliating the graphite oxide of the metal precursor-graphite oxide mixture with hydrogen to chemically modify the graphite oxide to form a hydrogen-exfoliated graphene sheet; and
while exfoliating the graphite oxide, simultaneously reducing the metal precursor in the metal precursor-graphite oxide mixture to adsorb metal nanoparticles on a first major surface of the hydrogen-exfoliated graphene sheet.
2. The method of claim 1 , wherein the metal nanoparticles comprise platinum (Pt), palladium (Pd), silver (Ag), gold (Au), nickel (Ni), titanium (Ti), tin (Sn), ruthenium (Ru), or combinations thereof.
3. The method of claim 1 , wherein the metal precursor comprises platinum (Pt), palladium (Pd), silver (Ag), gold (Au), nickel (Ni), titanium (Ti), tin (Sn), ruthenium (Ru), or combinations thereof.
4. The method of claim 1 , wherein the metal precursor comprises hexachloroplatinic acid (H 2 PtCl 6 .6H 2 O).
5. The method of claim 1 , wherein the liquid medium is water, acetone, ethanol, toluene, or combinations thereof.
6. The method of claim 1 , further comprising drying the metal precursor-graphite oxide mixture before exfoliating the graphite oxide of the metal precursor-graphite oxide mixture.
7. The method of claim 1 , wherein exfoliating the graphite oxide and reducing the metal precursor comprises:
contacting hydrogen gas (H 2 ) with oxygen-based functional groups of the graphite oxide within a reaction chamber to form the hydrogen-exfoliated graphene sheet; and
reducing the metal precursor using a hydrogen gas to attach the metal nanoparticles to the hydrogen-exfoliated graphene sheet.
8. The method of claim 7 , wherein a temperature within the reaction chamber is about 200° C. to about 600° C.
9. The method of claim 7 , wherein a flow rate of the hydrogen gas within the reaction chamber is about 50 sccm to about 200 sccm.
10. The method of claim 7 , wherein substantially 100% of the metal precursor is reduced to the metal nanoparticles attached to the hydrogen-exfoliated graphene sheet.
11. The method of claim 7 , wherein the metal precursor is reduced to the metal nanoparticles within about 10 seconds to about 15 seconds.
12. The method of claim 1 , wherein the metal precursor comprises hexachloroplatinic acid (H 2 PtCl 6 .6H 2 O) and the metal nanoparticles comprise platinum nanoparticles.
13. The method of claim 1 , wherein a density of graphene in the metal nanoparticle-graphene composite is about 0.5 g/cm 3 to about 0.8 g/cm 3 .
14. A mixture comprising:
a metal precursor;
graphite oxide;
hydrogen gas;
a liquid medium;
a hydrogen-exfoliated graphene sheet; and
a plurality of platinum nanoparticles dispersed on a first major surface of the hydrogen-exfoliated graphene sheet.
15. The mixture of claim 14 , wherein the metal precursor comprises platinum (Pt), palladium (Pd), silver (Ag), gold (Au), nickel (Ni), titanium (Ti), tin (Sn), ruthenium (Ru), or combinations thereof.
16. The mixture of claim 14 , wherein the metal precursor comprises hexachloroplatinic acid (H 2 PtCl 6 .6H 2 O).
17. The mixture of claim 14 , wherein the liquid medium is water, acetone, ethanol, toluene, or combinations thereof.
18. The mixture of claim 14 , wherein the hydrogen-exfoliated graphene sheet and the plurality of platinum nanoparticles dispersed on the first major surface of the hydrogen-exfoliated graphene sheet to form an electrocatalyst, an average size of the platinum nanoparticles of the platinum nanoparticles is about 3 nanometers to about 5 nanometers, and a current density of the electrocatalyst is at least about 1239 mA cm −2 .
19. The mixture of claim 18 , wherein the current density is measured at a voltage of 0.5 V.
20. The mixture of claim 14 , wherein an average particle size of the plurality of platinum nanoparticles is about 3.3 nanometers.