Organic electroluminescent element
View Patent ↗Provided is an organic electroluminescent device (organic EL device) that is improved in luminous efficiency, sufficiently secures driving stability, and has a simple construction. The organic electroluminescent device includes, between an anode and cathode laminated on a substrate, a plurality of organic layers. At least one layer of the organic layers contains a carbazole compound represented by the following general formula (1) having two to three structures in each of which a carbazole ring and a dibenzofuran or dibenzothiophene ring are bonded to each other at 1- and 4-positions. In the formula (1), A represents an n-valent aromatic hydrocarbon group or aromatic heterocyclic group, n represents an integer of 2 or 3, and X represents oxygen or sulfur.
1. An organic electroluminescent device, having a structure in which an anode, an organic layer, and a cathode are laminated on a substrate, wherein at least one layer selected from the group consisting of a light-emitting, layer, a hole-transporting layer, an electron-transporting layer, a hole-blocking layer, an electron-blocking layer, and an exciton-blocking layer contains a carbazole compound represented by the general formula (1):
wherein:
A represents an n-valent aromatic hydrocarbon group having 6 to 30 carbon atoms, an n-valent aromatic heterocyclic group having 3 to 30 carbon atoms, or an n-valent aromatic group in which two to six of the aromatic hydrocarbon groups and the aromatic heterocyclic groups are linked to each other;
n represents an integer of 2 or 3;
when the aromatic hydrocarbon group or the aromatic heterocyclic group has substituents, the substituents each independently comprise an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, —OAr, —N(Ar) 2 , or —Si(Ar) 3 ;
R's each independently represent hydrogen, an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 3 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, —OAr, —N(Ar) 2 , —Si(Ar) 3 , an aromatic hydrocarbon group having 6 to 10 carbon atoms, an aromatic heterocyclic group having 3 to 10 carbon atoms, or an aromatic group in which two to three of the aromatic hydrocarbon groups and the aromatic heterocyclic groups are linked to each other;
Ar's each independently represent an aromatic hydrocarbon group having 6 to 10 carbon atoms, an aromatic heterocyclic group having 3 to 10 carbon atoms, or an aromatic group in which two to three of the aromatic hydrocarbon groups and the aromatic heterocyclic groups are linked to each other; and
X's each independently represent oxygen or sulfur.
2. An organic electroluminescent device according to claim 1 , wherein R's each represent hydrogen.
3. An organic electroluminescent device according to claim 1 , wherein A represents an n-valent aromatic group represented by any one of the following formulae (2) to (5):
in the formulae (2) to (5):
Y's each independently represent C, C(R), or nitrogen, and n Y's each represent C, provided that n+1 Y's in the formula (4) each represent C; and
n and R each have the same meaning as that in the general formula (1).
4. An organic electroluminescent device according to claim 1 , wherein the layer containing the carbazole compound represented by the general formula (1) is a light-emitting layer containing a phosphorescent light-emitting dopant.